Base-free direct formylation of aromatic iodides using CO2 as C1 source catalyzed by palladium nanoparticles grafted onto amino-functionalized nanostarch

被引：17

作者：

Kumar, Subodh ^{[1
]}

Verma, Sanny ^{[1
]}

Jain, Suman L. ^{[1
]}

机构：

[1] Indian Inst Petr, CSIR, Div Chem Sci, Mohkampur 248005, Dehradun, India

来源：

TETRAHEDRON LETTERS | 2015年 / 56卷 / 19期

关键词：

Carbon dioxide; Heterogeneous catalyst; Formylation; Palladium; Nanomaterial; CARBON-DIOXIDE; REDUCTIVE CARBONYLATION; ARYL BROMIDES; HALIDES; MONOXIDE;

D O I：

10.1016/j.tetlet.2015.03.077

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly dispersed Pd-nanoparticles grafted onto amino-functionalized nanostarch were found to be excellent heterogeneous catalysts for the direct formylation of various aromatic iodides to their corresponding aldehydes in excellent yields without using any base. The developed catalyst could easily be recovered and recycled for several runs without any significant loss in activity and importantly, no metal leaching was occurred during the reaction. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：2430 / 2433

页数：4

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