Electrostatic control of aromatic stacking interactions

被引：280
|
作者：
Cockroft, SL
Hunter, CA [1 ]
Lawson, KR
Perkins, J
Urch, CJ
机构：
[1] Univ Sheffield, Krebs Inst Biomolec Res, Dept Chem, Ctr Chem Biol, Sheffield S3 7HF, S Yorkshire, England
[2] Jealotts Hill Int Res Ctr, Syngenta, Bracknell RG42 6EY, Berks, England
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 24期
关键词：
D O I：
10.1021/ja050880n
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A supramolecular approach has been used to investigate the free energies of intermolecular aromatic stacking interactions. Chemical double mutant cycles have been used to measure the effect of a range of substituents on face-to-face stacking interactions with phenyl and pentafluorophenyl rings. Electrostatic effects dominate the trends in interaction energy. Copyright © 2005 American Chemical Society.
引用
收藏
页码：8594 / 8595
页数：2
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