Researches on the α-Aminoxylation between α-Azoleketones and 2,2,6,6-Tetramethylpiperidine-1-oxyl with Cu/O2

被引：0

作者：

Zhou, Peng ^{[1
]}

Qiu, Huihua ^{[1
]}

Pan, Hongcheng ^{[1
]}

Shi, Jicheng ^{[1
]}

Zhou, Jianmin ^{[1
]}

机构：

[1] Guangdong Univ Petrochem Technol, Sch Chem Engn, Maoming 525000, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 36卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Cu catalyzed; dioxygen; alpha-azoleketone; 2,2,6,6-tetramethylpiperidine-1-oxyl; alpha-aminoxylation; C-H BOND; 1,3-DICARBONYL COMPOUNDS; OXIDATION; DESIGN; INHIBITORS; TEMPO; ACIDS;

D O I：

10.6023/cjoc201601019

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The alpha-aminoxylation between alpha-azoleketones and 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) was studied in this paper. Taking Cu(II) salts as catalyst and air as oxidant, a number of alkoxyamines have been synthesized via alpha-aminoxylation between alpha-azoleketones and TEMPO in good yields at room temperature. This strategy is highlighted by appealing features such as mild reaction condition, inexpensive catalyst, green oxidant and good yield.

引用

页码：1596 / 1601

页数：6