Plywood-like structure of injection-moulded polypropylene

被引:42
|
作者
Yamaguchi, Masayuki [1 ]
Irie, Yuta [1 ]
Phulkerd, Panitha [1 ]
Hagihara, Hiroki [1 ]
Hirayama, Soichiro [1 ]
Sasaki, Shintaro [2 ]
机构
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Nomi, Ishikawa 9231292, Japan
[2] Japan Adv Inst Sci & Technol, Ctr Nano Mat & Technol, Nomi, Ishikawa 9231292, Japan
关键词
Molecular orientation; Polypropylene; Injection-moulding; BETA-ISOTACTIC POLYPROPYLENE; X-RAY-DIFFRACTION; POLYMER CRYSTALLIZATION; MOLECULAR-ORIENTATION; PHASE-TRANSFORMATION; NUCLEATING-AGENTS; N,N'-DICYCLOHEXYL-2,6-NAPHTHALENEDICARBOXAMIDE; MORPHOLOGY; BEHAVIOR; GROWTH;
D O I
10.1016/j.polymer.2010.10.007
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Injection-moulded products having unique structure, in which the direction of molecular orientation in the skin layer is perpendicular to that in the core layer, are developed employing isotactic polypropylene with a nucleating agent. The extraordinary three-layered structure with beta trigonal crystal form in the core layer, which shows higher impact strength than the conventional alpha monoclinic form, leads to high level of toughness. Moreover, an injection-moulded product having five-layered structure is also demonstrated in this paper. Because of the complicated crack propagation nature due to the abrupt change of molecular orientation, which avoids fractured pieces with sharp-edge, the products with plywood-like structure will be employed in various applications to improve the safety. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5983 / 5989
页数:7
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