Plywood-like structure of injection-moulded polypropylene

被引:42
|
作者
Yamaguchi, Masayuki [1 ]
Irie, Yuta [1 ]
Phulkerd, Panitha [1 ]
Hagihara, Hiroki [1 ]
Hirayama, Soichiro [1 ]
Sasaki, Shintaro [2 ]
机构
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Nomi, Ishikawa 9231292, Japan
[2] Japan Adv Inst Sci & Technol, Ctr Nano Mat & Technol, Nomi, Ishikawa 9231292, Japan
关键词
Molecular orientation; Polypropylene; Injection-moulding; BETA-ISOTACTIC POLYPROPYLENE; X-RAY-DIFFRACTION; POLYMER CRYSTALLIZATION; MOLECULAR-ORIENTATION; PHASE-TRANSFORMATION; NUCLEATING-AGENTS; N,N'-DICYCLOHEXYL-2,6-NAPHTHALENEDICARBOXAMIDE; MORPHOLOGY; BEHAVIOR; GROWTH;
D O I
10.1016/j.polymer.2010.10.007
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Injection-moulded products having unique structure, in which the direction of molecular orientation in the skin layer is perpendicular to that in the core layer, are developed employing isotactic polypropylene with a nucleating agent. The extraordinary three-layered structure with beta trigonal crystal form in the core layer, which shows higher impact strength than the conventional alpha monoclinic form, leads to high level of toughness. Moreover, an injection-moulded product having five-layered structure is also demonstrated in this paper. Because of the complicated crack propagation nature due to the abrupt change of molecular orientation, which avoids fractured pieces with sharp-edge, the products with plywood-like structure will be employed in various applications to improve the safety. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5983 / 5989
页数:7
相关论文
共 50 条
  • [21] OPTIMUM DESIGN OF INJECTION-MOULDED ANGLE BARS.
    Mosle, H.G.
    Schmidt, H.F.
    Fortunas, A.
    1978, 68 (07): : 9 - 10
  • [22] Yield stress distribution in injection-moulded glassy polymers
    Verbeeten, Wilco M. H.
    Kanters, Marc J. W.
    Engels, Tom A. P.
    Govaert, Leon E.
    POLYMER INTERNATIONAL, 2015, 64 (11) : 1527 - 1536
  • [23] Mechanical characterization of thin injection-moulded polypropylene specimens under large in-plane shear deformations
    Codolini, A.
    Li, Q. M.
    Wilkinson, A.
    POLYMER TESTING, 2018, 69 : 485 - 489
  • [24] Efficiency of injection-moulded polymer composite spur gears
    Senthilvelan, S.
    Gnanamoorthy, R.
    PROCEEDINGS OF THE INSTITUTION OF MECHANICAL ENGINEERS PART J-JOURNAL OF ENGINEERING TRIBOLOGY, 2009, 223 (J6) : 925 - 928
  • [25] Effect of the Extrusion Process on the Morphology and Electrical Conductivity of Injection-Moulded Polypropylene/HDPE/Carbon Black Composites
    Liu, Zheng-Ying
    Gao, Yong-Juan
    Yin, Chao-Lu
    Huang, Shi-Lin
    Yang, Ming-Bo
    POLYMERS & POLYMER COMPOSITES, 2012, 20 (04): : 359 - 366
  • [26] Processing-induced morphology: Its relationship with tensile-impact behaviour in injection-moulded polypropylene
    LaFranche, Eric
    Brassart, Gregory
    Krawczak, Patricia
    POLYMERS & POLYMER COMPOSITES, 2006, 14 (06): : 563 - 576
  • [27] The role of interface modification on the mechanical properties of injection-moulded composites from commingled polypropylene/banana granules
    Paul, Sherely Annie
    Reussmann, Thomas
    Mennig, Guenter
    Lampke, Thomas
    Pothen, Laly A.
    Mathew, G. D. Gem
    Joseph, Kuruvilla
    Thomas, Sabu
    COMPOSITE INTERFACES, 2007, 14 (7-9) : 849 - 867
  • [29] Flow analysis of injection-moulded parts with cylindrical microfeatures
    Cui, Z.
    Peng, Y.
    Liu, C.
    Shen, C.
    PROCEEDINGS OF THE INSTITUTION OF MECHANICAL ENGINEERS PART C-JOURNAL OF MECHANICAL ENGINEERING SCIENCE, 2012, 226 (C6) : 1612 - 1619
  • [30] Dynamic mechanical analysis of injection-moulded discs of polypropylene and untreated and silane-treated talc-filled polypropylene composites
    Díez-Gutiérrez, S
    Rodríguez-Pérez, MA
    De Saja, JA
    Velasco, JI
    POLYMER, 1999, 40 (19) : 5345 - 5353