Latest development of double perovskite electrode materials for solid oxide fuel cells: a review

被引:127
作者
Afroze, Shammya [1 ]
Karim, AfizulHakem [1 ]
Cheok, Quentin [1 ]
Eriksson, Sten [2 ]
Azad, Abul K. [1 ]
机构
[1] Univ Brunei Darussalam, Fac Integrated Technol, Jalan Tunku Link, BE-1410 Gadong, Brunei
[2] Chalmers Univ Technol, Dept Chem & Chem Engn, Energy & Mat Environm Inorgan Chem, SE-41296 Gothenburg, Sweden
关键词
double perovskites; electrode materials; hydrocarbon fuel; solid oxide fuel cells; PROTON-CONDUCTING ELECTROLYTES; NEUTRON POWDER DIFFRACTION; HIGH-PERFORMANCE CATHODE; ELECTROCHEMICAL PERFORMANCE; ANODE MATERIALS; LAYERED-PEROVSKITE; MAGNETIC-PROPERTIES; ELECTRICAL-CONDUCTIVITY; COMPOSITE CATHODES; PHASE-TRANSITION;
D O I
10.1007/s11708-019-0651-x
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Recently, the development and fabrication of electrode component of the solid oxide fuel cell (SOFC) have gained a significant importance, especially after the advent of electrode supported SOFCs. The function of the electrode involves the facilitation of fuel gas diffusion, oxidation of the fuel, transport of electrons, and transport of the byproduct of the electrochemical reaction. Impressive progress has been made in the development of alternative electrode materials with mixed conducting properties and a few of the other composite cermets. During the operation of a SOFC, it is necessary to avoid carburization and sulfidation problems. The present review focuses on the various aspects pertaining to a potential electrode material, the double perovskite, as an anode and cathode in the SOFC. More than 150 SOFCs electrode compositions which had been investigated in the literature have been analyzed. An evaluation has been performed in terms of phase, structure, diffraction pattern, electrical conductivity, and power density. Various methods adopted to determine the quality of electrode component have been provided in detail. This review comprises the literature values to suggest possible direction for future research.
引用
收藏
页码:770 / 797
页数:28
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