A general ruthenium-catalyzed synthesis of aromatic Amines

被引：167

作者：

Hollmann, Dirk ^{[1
]}

Baehn, Sebastian ^{[1
]}

Tillack, Annegret ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse, D-18509 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 43期

关键词：

aminations; aniline; homogeneous catalysis; ruthenium; Shvo catalyst;

D O I：

10.1002/anie.200703119

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Simple as that: The synthesis of aromatic amines from aliphatic amines proceeds under transfer hydrogenation conditions (see scheme). By applying the Shvo catalyst, general applicability is shown in the conversion of a variety of functionalized anilines and aliphatic amines. This base- and salt-free method can be an excellent alternative to the known synthesis of anilines. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8291 / 8294

页数：4

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