Liquid-liquid equilibrium of acetic acid - ethanol - ethyl acetate water quaternary system: Data review and new results at 323.15 K and 333.15 K

被引：17
作者：
Trofimova, Maya [1 ]
Sadaev, Alexey [1 ]
Samarov, Artemiy [1 ]
Golikova, Alexandra [1 ]
Tsvetov, Nikita [1 ,2 ]
Toikka, Maria [1 ]
Toikka, Alexander [1 ]
机构：
[1] St Petersburg State Univ, Dept Chem Thermodynam & Kinet, Univ Skiy Prospect 26, St Petersburg 198504, Russia
[2] Russian Acad Sci, Kola Res Ctr, Tananaev Inst Rare Element & Mineral Chem & Techn, Acad Town 26a, Apatity 184209, Murmansk Region, Russia
来源：
FLUID PHASE EQUILIBRIA | 2020年 / 503卷
基金：
俄罗斯基础研究基金会;
关键词：
Solubility; Liquid-liquid equilibrium; Critical state; Quaternary system; Ethyl acetate; VAPOR-LIQUID; CRITICAL STATES; PHASE-EQUILIBRIA; PLUS WATER; SOLUBILITY INFLUENCES; TERNARY-SYSTEMS; BUTYL ACETATE; MIXTURES; ALCOHOL; ESTER;
D O I：
10.1016/j.fluid.2019.112321
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
A brief review of data on solubility and liquid-liquid equilibrium (LLE) in the acetic acid - ethanol - ethyl acetate - water system is presented. A new set of experimental data on solubility, LLE, and critical phases in this quaternary system, ternary subsystems (acetic acid - ethyl acetate - water, ethanol - ethyl acetate - water) and binary subsystem ethyl acetate - water are presented for 323.15 K and 333.15 K at atmospheric pressure. The gas chromatography and the cloud point technique were used to obtain experimental data. Binodal curves, surfaces, and critical manifolds are presented including 3D phase diagrams in composition tetrahedron. Experimental LLE data were correlated using the NRTL model. (C) 2019 Elsevier B.V. All rights reserved.
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页数：11
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