Polyoxomolybdate-stabilized Cu2O nanoparticles as an efficient catalyst for the azide-alkyne cycloaddition

被引：19

作者：

Amini, Mojtaba ^{[1
]}

Naslhajian, Hadi ^{[1
,2
]}

Farnia, S. Morteza F. ^{[2
]}

Kang, Hee Kyoung ^{[3
]}

Gautam, Sanjeev ^{[4
]}

Chae, Keun Hwa ^{[3
]}

机构：

[1] Univ Maragheh, Fac Sci, Dept Chem, POB 55181-83111731, Maragheh, Iran

[2] Univ Tehran, Dept Chem, Tehran, Iran

[3] Korea Inst Sci & Technol, Adv Anal Ctr, Seoul 136791, South Korea

[4] Punjab Univ, Univ Inst Chem Engn & Technol SSB UICET, Chandigarh 160014, India

来源：

NEW JOURNAL OF CHEMISTRY | 2016年 / 40卷 / 06期

关键词：

METAL-ORGANIC FRAMEWORK; CLICK CHEMISTRY; COPPER(I) OXIDE; GROWING APPLICATIONS; 1,2,3-TRIAZOLES; REACTIVITY; INSIGHTS;

D O I：

10.1039/c6nj00868b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a simple methodology for the stabilization of Cu2O nanoparticles of size 10-30 nm on the polar pore surface of the polyoxomolybdate (NH4)(12)[Mo-36(NO)(4)O-108(H2O)(16)] ({Mo-36}). For the first time, a Cu2O@{Mo-36} composite has been utilized as a recyclable catalyst for the Huisgen 1,3-dipolar cycloaddition reaction of terminal alkynes, aryl/alkyl halides and NaN3 for the synthesis of 1,2,3-triazoles.

引用

页码：5313 / 5317

页数：5

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