Influence of post-sintering annealing on relaxor behaviour of (Pb0.75Ba0.25)(Zr0.70Ti0.30)O3 ceramics

被引:17
作者
Adamczyk, M [1 ]
Ujma, Z [1 ]
Szymczak, L [1 ]
Koperski, J [1 ]
机构
[1] Silesian Univ, Inst Phys, PL-40007 Katowice, Poland
关键词
dielectric properties; relaxer ferroelectrics; annealing conditions; ceramics;
D O I
10.1016/j.ceramint.2004.09.005
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The dielectric and relaxor properties of lead-barium-zirconate-titanate (PBZT) ceramics of composition Ba/Zr/Ti:25/70/30 has been studied as-prepared (unannealed) as well as after annealing at 1000 degrees C for 20, 40 and 60 min, respectively. After the annealing treatment the Pb deficiency for the studied ceramics was found. The influence of a post-sintering annealing on the values of characteristic parameters describing a relaxor behaviour of the studied ceramics (epsilon'(max), T-m, T-f, T-B) was determined. The temperature T-m shifts towards the lower value and the dielectric constant increases after annealing. The general trend seems to indicate that the annealing broadens the temperature region of the specific relaxor properties occurrence. (c) 2004 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:791 / 794
页数:4
相关论文
共 12 条
  • [1] Relaxor behavior of La-modified (Pb0.75Ba0.25)(Zr0.70Ti0.30)O3 ceramics
    Adamczyk, M
    Ujma, Z
    Handerek, J
    [J]. JOURNAL OF APPLIED PHYSICS, 2001, 89 (01) : 542 - 547
  • [2] KINETICS OF COMPOSITIONAL ORDERING IN PB2B'B'' O-6 CRYSTALS
    BOKOV, AA
    RAYEVSKII, IP
    SMOTRAKOV, VG
    PROKOPALO, OI
    [J]. PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1986, 93 (02): : 411 - 417
  • [3] Structure of the dielectric spectrum of relaxor ferroelectrics
    Bovtun, V
    Petzelt, J
    Porokhonskyy, V
    Kamba, S
    Yakimenko, Y
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2001, 21 (10-11) : 1307 - 1311
  • [4] Temperature dependence of the dielectric constant of relaxor ferroelectrics
    Cheng, ZY
    Katiyar, RS
    Yao, X
    Bhalla, AS
    [J]. PHYSICAL REVIEW B, 1998, 57 (14) : 8166 - 8177
  • [5] DYNAMICS OF THE FREEZING PROCESS IN RELAXOR FERROELECTRICS
    GUI, H
    GU, BL
    ZHANG, XW
    [J]. PHYSICAL REVIEW B, 1995, 52 (05): : 3135 - 3142
  • [6] Dielectric and pyroelectric properties of (Pb1-xBax) (Zr0.70Ti0.30) O3 [x=0.25÷0.35] ceramics exhibiting the relaxor ferroelectrics behaviour
    Handerek, J
    Adamczyk, M
    Ujma, Z
    [J]. FERROELECTRICS, 1999, 233 (3-4) : 253 - 270
  • [7] INFINITE-RANGED MODELS OF SPIN-GLASSES
    KIRKPATRICK, S
    SHERRINGTON, D
    [J]. PHYSICAL REVIEW B, 1978, 17 (11): : 4384 - 4403
  • [8] Li G., 1995, Ferroelectrics, V166, P31, DOI 10.1080/00150199508223570
  • [9] GRAIN-SIZE EFFECTS ON PROPERTIES OF SOME FERROELECTRIC CERAMICS
    MARTIREN.HT
    BURFOOT, JC
    [J]. JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1974, 7 (17): : 3182 - 3192
  • [10] Effect of post sinter annealing on the dielectric constants of PMN and PFN
    Mohan, D
    Prasad, R
    Banerjee, S
    [J]. CERAMICS INTERNATIONAL, 2001, 27 (02) : 243 - 246