Thermal, solution and structural studies of a 3D Ag(I) coordination polymer with various Ag-Ag bonds, [Ag3(μ-Hbtc)(μ-H2btc)]n

被引：29

作者：

Akhbari, K. ^{[1
]}

Morsali, A. ^{[1
]}

机构：

[1] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran, Iran

来源：

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2008年 / 5卷 / 01期

关键词：

silver(I); 1,3,5-benzenetricarboxylic acid; Ag-Ag interaction; coordination polymer; solution; thermal study;

D O I：

10.1007/BF03245814

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Ag-3(mu-H(2)btc)(mu-H(2)btc)](n) (H(3)btc = 1,3,5-benzenetricarboxylic acid) (1), a new rarely reported Ag(I) three-dimensional coordination polymer with several Ag-Ag bonds, has been synthesized, characterized by elemental analysis and IR spectroscopy and its structure determined by single-crystal X-ray diffraction. The thermal stability of compound 1 was studied by thermal gravimetric and differential thermal analyses. The single crystal X-ray analysis of compound 1 shows that the complex consists of [Ag-3(mu-Hbtc)(mu-H(2)btc)] subunits containing four different Ag environments. The results of studies of the stoichiometry and complex formation in methanol solution supported their solid state stoichiometry.

引用

页码：48 / 56

页数：9

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