Thermal, solution and structural studies of a 3D Ag(I) coordination polymer with various Ag-Ag bonds, [Ag3(μ-Hbtc)(μ-H2btc)]n

被引:29
作者
Akhbari, K. [1 ]
Morsali, A. [1 ]
机构
[1] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran, Iran
关键词
silver(I); 1,3,5-benzenetricarboxylic acid; Ag-Ag interaction; coordination polymer; solution; thermal study;
D O I
10.1007/BF03245814
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
[Ag-3(mu-H(2)btc)(mu-H(2)btc)](n) (H(3)btc = 1,3,5-benzenetricarboxylic acid) (1), a new rarely reported Ag(I) three-dimensional coordination polymer with several Ag-Ag bonds, has been synthesized, characterized by elemental analysis and IR spectroscopy and its structure determined by single-crystal X-ray diffraction. The thermal stability of compound 1 was studied by thermal gravimetric and differential thermal analyses. The single crystal X-ray analysis of compound 1 shows that the complex consists of [Ag-3(mu-Hbtc)(mu-H(2)btc)] subunits containing four different Ag environments. The results of studies of the stoichiometry and complex formation in methanol solution supported their solid state stoichiometry.
引用
收藏
页码:48 / 56
页数:9
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