Catalytic Enantioselective Conjugate Allylation of Unsaturated Methylidene Ketones

被引：31

作者：

Brozek, Laura A. ^{[1
]}

Sieber, Joshua D. ^{[1
]}

Morken, James P. ^{[1
]}

机构：

[1] Boston Coll, Dept Chem, Merkert Chem Ctr, Chestnut Hill, MA 02467 USA

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 05期

关键词：

ACTIVATED ENONES; PALLADIUM; LIGANDS; PHOSPHORAMIDITES; COMPLEXES; EFFICIENT; ADDITIONS; FACILE;

D O I：

10.1021/ol102982b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The use of unsaturated methylidene ketones in catalytic conjugate allylations allows a significant expansion in substrate scope and, with appropriate chiral ligands, occurs in a highly enantioselective fashion.

引用

页码：995 / 997

页数：3

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