Crystal structures of the octahedral rhenium cluster compexes Cs4[Re6S8(OH)6]•6H2O and Cs4[Re6Se8(OH)6]•8H2O

被引：19

作者：

Brylev, K. A. ^{[1
,2
]}

Mironov, Yu. V. ^{[1
]}

Kim, S. -J. ^{[2
]}

Fedorov, V. E. ^{[1
]}

机构：

[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia

[2] Ewha Womans Univ, Seoul, South Korea

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2007年 / 48卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

octahedral cluster; rhenium; synthesis; crystal structure; hydrate;

D O I：

10.1007/s10947-007-0179-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The salts Cs-4[Re6S8(OH)(6)]center dot 6H(2)O (1) and Cs-4[Re6Se8(OH)(6)]center dot 8H(2)O (2) were obtained by the reactions of Re6S8Br2 and Re6Se8Br2 with a CsOH melt with further solution of the products in water and crystallization of 1 and 2 from the aqueous solutions. The structure of the compounds was established by X-ray single crystal diffraction analysis. Compound 1 crystallizes in the orthorhombic space group Pbca with unit cell parameters a = 14.175(2) angstrom, b = 11.321(2) angstrom, c = 17.503(2) angstrom, V = 2808.5(7) angstrom(3), Z = 4, d(calc) = 5.003 g/cm(3); compound 2 crystallizes in the triclinic space group P (1) over bar with unit cell parameters a = 9.020(4) angstrom, b = 9.127(4) angstrom, c = 10.289(4) angstrom, alpha = 79.589(7)degrees, beta = 75.829(7)degrees, gamma = 72.186(7)degrees, V = 776.8(6) angstrom(3), Z = 1, d(calc) = 5.402 g/cm(3).

引用

页码：1118 / 1123

页数：6

共 17 条

[1] Cyano-bridged Re6Q8 (Q = S, Se) Cluster-Cobalt(II) framework materials:: Versatile solid chemical sensors [J].

Beauvais, LG ;

Shores, MP ;

Long, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (12) :2763-2772

[2] Expanded Prussian blue analogues incorporating [Re6Se8(CN)6]3-/4- clusters:: Adjusting porosity via charge balance [J].

Bennett, MV ;

Beauvais, LG ;

Shores, MP ;

Long, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (33) :8022-8032

[3] Inorganic coordination polymers based on chalcocyanide cluster complexes [J].

Fedorov, VE ;

Naumov, NG ;

Mironov, YV ;

Virovets, AV ;

Artemkina, SB ;

Brylev, KA ;

Yarovoi, SS ;

Efremova, OA ;

Peak, UH .

JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 43 (04) :669-684

[4] STRUCTURE AND PHOTOELECTROCHEMICAL PROPERTIES OF SEMICONDUCTING RHENIUM CLUSTER CHALCOGENIDES - RE6X8BR2 (X = S, SE) [J].

FISCHER, C ;

ALONSOVANTE, N ;

FIECHTER, S ;

TRIBUTSCH, H ;

RECK, G ;

SCHULZ, W .

JOURNAL OF ALLOYS AND COMPOUNDS, 1992, 178 :305-314

[5] Primitive cubic packing of anions in Cs4[Re6Te8(CN)6]•2H2O and Ba2[Re6Te8(CN)6]•12H2O crystals [J].

Imoto, H ;

Naumov, NG ;

Virovets, AV ;

Saito, T ;

Fedorov, VE .

JOURNAL OF STRUCTURAL CHEMISTRY, 1998, 39 (05) :720-727

[6] Crystal structure of the two-dimensional framework [Mn(salen)]4n[Re6Te8(CN)6]n [salen = N,N′-ethylenebis(salicylideneaminato)] [J].

Kim, Y ;

Park, SM ;

Nam, W ;

Kim, SJ .

CHEMICAL COMMUNICATIONS, 2001, (16) :1470-1471

[7] The first coordination polymers based on octahedral hexahydroxo rhenium cluster complexes [Re6Q8(OH)6]4- (Q = S, Se) and alkaline earth metal cations [J].

Mironov, YV ;

Fedorov, VE ;

Bang, HJ ;

Kim, SJ .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 3 (03) :553-557

[8] Redetermination of the crystal structure of potassium peroxodisulfate (K2S2O8) [J].

Naumov, DY ;

Virovets, AV ;

Podberezskaya, NV ;

Novikov, PB ;

Politov, AA .

JOURNAL OF STRUCTURAL CHEMISTRY, 1997, 38 (05) :772-778

[9]

Naumov N. G., 1999, UKR KHIM ZH, V65, P21

[10]

Naumov NG, 1998, ANGEW CHEM INT EDIT, V37, P1943, DOI 10.1002/(SICI)1521-3773(19980803)37:13/14<1943::AID-ANIE1943>3.0.CO

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