A BINOL Based Fluorescence Sensor for Distinction of D-Glucose

被引：9

作者：

Xu, Bangyu ^{[1
]}

Hou, Jiting ^{[1
]}

Li, Kun ^{[1
]}

Lu, Zhengwei ^{[1
]}

Yu, Xiaoqi ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Minist Educ, Chengdu 610064, Sichuan, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2015年 / 33卷 / 01期

基金：

美国国家科学基金会;

关键词：

1,1 '-binaphthol; boronic acid; D-glucose; distinction; BORONIC ACID; RECOGNITION; CHEMOSENSORS; RECEPTOR; CHEMODOSIMETER; SACCHARIDES; COMPLEXES; ANION;

D O I：

10.1002/cjoc.201400120

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A saccharide fluorescent receptor based on 1,1 '-binaphthol was developed. The boronic acids groups are directly attached to the 3,3 '-positions of BINOL which acted as probes to saccharides. The methyl protected receptor R1 showed better response to D-fructose compared to other saccharides in the fluorescence quenching experiment. To improve the selectivity of D-glucose, the triethylene glycol protected receptor R2 was developed. Receptor R2 has a better water-solubility than R1 that can be applied in completely aqueous environment. With receptor R2, D-glucose has a different response to other saccharides that can be useful for the distinction of D-glucose.

引用

页码：101 / 106

页数：6

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