Electroluminescence Enhancement by Modifying Poly[9,9-di-(2′-ethylhexyl)fluorenyl-2,7-diyl]

被引:0
作者
Zhang, Qiushu [1 ]
Zhang, Sihui [2 ]
Peng, Bei [1 ]
机构
[1] Univ Elect Sci & Technol China, Sch Mechatron Engn, Chengdu 611731, Sichuan, Peoples R China
[2] Xihua Univ, Sch Mech Engn, Chengdu, Sichuan, Peoples R China
关键词
Blending; Electroluminescence; End-capping; Polyfluorene; LIGHT-EMITTING-DIODES; CONJUGATED-POLYMER BLENDS; FORSTER ENERGY-TRANSFER; POLYFLUORENE; PERFORMANCE; EFFICIENCY; EMISSION; PHOTOPHYSICS; COPOLYMERS; MORPHOLOGY;
D O I
10.1080/03602559.2010.512352
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We report on the fabrication and characterization of light emitting diodes based on pristine or modified poly[9,9-di-(2'-ethylhexyl)fluorenyl-2,7-diyl]. The modified polyfluorene was formed by blending with the hole transport material poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(N,N'-bis(4-butylphenyl-1,1'-biphenylene-4,4'-diamine))], or endcapping with dimethylphenyl. The addition of the hole-transporting polymer to the host polymer or the attachment of the end-capper to the polymer chain improved device properties. Phase-separated domains in blend thin film morphology were observed in scanning electron microscope pictures. These domains may play a role in the improved device performance. The introduction of the hole-transporting polymer or the end-capper also improved blue emission.
引用
收藏
页码:67 / 72
页数:6
相关论文
共 28 条
[1]   Temperature- and field-dependent electron and hole mobilities in polymer light-emitting diodes [J].
Bozano, L ;
Carter, SA ;
Scott, JC ;
Malliaras, GG ;
Brock, PJ .
APPLIED PHYSICS LETTERS, 1999, 74 (08) :1132-1134
[2]   Effect of poly(3,4-ethylene dioxythiophene) on the built-in field in polymer light-emitting diodes probed by electroabsorption spectroscopy [J].
Brown, TM ;
Kim, JS ;
Friend, RH ;
Cacialli, F ;
Daik, R ;
Feast, WJ .
SYNTHETIC METALS, 2000, 111 :285-287
[3]   Polyfluorenes containing 1,8-naphthalimide dye as endcapping groups [J].
Cao, JX ;
Zhou, QG ;
Cheng, YX ;
Geng, YH ;
Wang, LX ;
Ma, DG ;
Jing, XB ;
Wang, FS .
SYNTHETIC METALS, 2005, 152 (1-3) :237-240
[4]   Polymer blend LEDs using polyfluorene copolymers and thermally cross-linked fluoropolymers [J].
Casasanta, V ;
Londergan, T ;
Dinu, R .
ORGANIC PHOTONIC MATERIALS AND DEVICES VI, 2004, 5351 :217-225
[5]   Correlating structure with fluorescence emission in phase-separated conjugated-polymer blends [J].
Chappell, J ;
Lidzey, DG ;
Jukes, PC ;
Higgins, AM ;
Thompson, RL ;
O'Connor, S ;
Grizzi, I ;
Fletcher, R ;
O'Brien, J ;
Geoghegan, M ;
Jones, RAL .
NATURE MATERIALS, 2003, 2 (09) :616-621
[6]   Luminescence properties of polyfluorenes blends [J].
Charas, A ;
Morgado, J ;
Alcácer, L ;
Martinho, JMG ;
Cacialli, F .
SYNTHETIC METALS, 2003, 137 (1-3) :1039-1040
[7]   Single-layer triplet white polymer light-emitting diodes incorporating polymer oxides: Effect of charge trapping at phosphorescent dopants [J].
Chen, Fang-Chung ;
Chien, Shang-Chieh ;
Chen, Yung-Shiuan .
APPLIED PHYSICS LETTERS, 2009, 94 (04)
[8]   New, efficient light emitting polymer diode for flat panel display applications [J].
Cinà, S ;
Baynes, N ;
Moons, E ;
Friend, RH ;
Burroughes, J ;
Towns, C ;
Heeks, K ;
O'Dell, R ;
O'Connor, S ;
Athanassopoulou, N .
ORGANIC PHOTONIC MATERIALS AND DEVICES III, 2001, 4279 :221-228
[9]   Efficient light emitting diodes from polyfluorene copolymer blends [J].
Cirpan, A ;
Ding, LM ;
Karasz, FE .
SYNTHETIC METALS, 2005, 150 (02) :195-198
[10]   Effect of Forster energy transfer and hole transport layer on performance of polymer light-emitting diodes [J].
Ding, LM ;
Karasz, FE ;
Lin, ZQ ;
Zheng, M ;
Liao, L ;
Pang, Y .
MACROMOLECULES, 2001, 34 (26) :9183-9188