Synthesis and structure of new thorium phosphate CaGdTh(PO4)3

被引:6
|
作者
Orlova, MP
Orlova, AI
Gobechiya, ER
Kabalov, YK
Dorokhova, GI
机构
[1] Nizhni Novgorod State Univ, Dept Chem, Nizhnii Novgorod 603950, Russia
[2] Moscow State Pedag Univ, Fac Geol, Moscow 119992, Russia
基金
俄罗斯基础研究基金会;
关键词
Oxide; Crystal Structure; Comparative Analysis; Cerium; Thermal Treatment;
D O I
10.1134/1.1857244
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Phosphate CaGdTh(pO(4))(3) was prepared by thermal treatment of a mixture of oxides. The final temperature was 1400degreesC. The phosphate was characterized by powder X-ray diffraction analysis and IR spectroscopy. The crystal structure was studied by the Rietveld method. The compound crystallizes in the monazite structure type (sp. gr. P2(1)/n). A comparative analysis of the structures of this phosphate and cerium orthophosphate CePO4 was carried out. (C) 2005 Pleiades Publishing, Inc.
引用
收藏
页码:48 / 51
页数:4
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