Critical exponents in the Lin-Taylor model of asymmetrical associating binary mixtures

被引:7
|
作者
Romero-Enrique, JM [1 ]
Ponce, IR
Rull, LF
Marconi, UMB
机构
[1] Univ Seville, Area Fis Teor, Dept Fis Atom Mol & Nucl, Aptdo 1065, E-41080 Seville, Spain
[2] Univ Camerino, Dipartimento Matemat & Fis, I-62032 Camerino, Italy
[3] Univ Camerino, Ist Nazl Fis Mat, I-62032 Camerino, Italy
关键词
D O I
10.1080/00268979809483190
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The critical behaviour of an associating fluid mixture, the so called Lin-Taylor model, has been studied, with focus on the critical exponents which characterize different points on the critical manifold. In general the critical behaviour of the mixture is found to be Ising-like, but there are some special situations: when two ordinary critical points merge into a double critical point or three critical points coalesce at a critical inflection point. A check has been made on the validity of the relations between critical exponents and predictions from the scaling laws.
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页码:571 / 577
页数:7
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