Porous Co3O4 nanotubes derived from Co4(CO)12 clusters on carbon nanotube templates:: A highly efficient material for Li-battery applications

被引:417
作者
Du, Ning [1 ,2 ]
Zhang, Hui [1 ,2 ]
Chen, Bindi [1 ,2 ]
Wu, Jianbo [1 ,2 ]
Ma, Xiangyang [1 ,2 ]
Liu, Zhihong [1 ,2 ]
Zhang, Yiqiang [1 ,2 ]
Yang, Deren [1 ,2 ]
Huang, Xiaohua [1 ,2 ]
Tu, Jiangping [1 ,2 ]
机构
[1] Zhejiang Univ, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
[2] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
关键词
D O I
10.1002/adma.200602513
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Co(3)O(4)peration. Porous and polycrystalline Co3O4 nanotubes have been derived from Co-4(CO)(12) clusters on carbon nanotube templates. The prepared porous Co3O4 nanotubes exhibit superior Li-battery performance with good cycle life and high capacity (1200 mAh g(-1)) owing to their hollow structure and small size. Moreover, this approach can be extended to synthesize other porous metal oxide nanotubes.
引用
收藏
页码:4505 / +
页数:6
相关论文
共 33 条
[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[2]   Heterostructures of ZnO nanorods with various one-dimensional nanostructures [J].
Bae, SY ;
Seo, HW ;
Choi, HC ;
Park, J ;
Park, J .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (33) :12318-12326
[3]   α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications [J].
Chen, J ;
Xu, LN ;
Li, WY ;
Gou, XL .
ADVANCED MATERIALS, 2005, 17 (05) :582-+
[4]   Porous indium oxide nanotubes:: Layer-by-layer assembly on carbon-nanotube templates and application for room-temperature NH3 gas sensors [J].
Du, Ning ;
Zhang, Hui ;
Chen, Bindi ;
Ma, Xiangyang ;
Liu, Zhihong ;
Wu, Jianbo ;
Yang, Deren .
ADVANCED MATERIALS, 2007, 19 (12) :1641-+
[5]   Preparation and electrochemical performance of polycrystalline and single crystalline CuO nanorods as anode materials for Li ion battery [J].
Gao, XP ;
Bao, JL ;
Pan, GL ;
Zhu, HY ;
Huang, PX ;
Wu, F ;
Song, DY .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (18) :5547-5551
[6]   Simple synthesis of hollow tin dioxide microspheres and their application to lithium-ion battery anodes [J].
Han, SJ ;
Jang, BC ;
Kim, T ;
Oh, SM ;
Hyeon, T .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (11) :1845-1850
[7]   Coating single-walled carbon nanotubes with tin oxide [J].
Han, WQ ;
Zettl, A .
NANO LETTERS, 2003, 3 (05) :681-683
[8]   Controlled synthesis of Co3O4 nanoparticles through oriented aggregation [J].
He, T ;
Chen, DR ;
Jiao, XL .
CHEMISTRY OF MATERIALS, 2004, 16 (04) :737-743
[9]   Tin-based amorphous oxide: A high-capacity lithium-ion-storage material [J].
Idota, Y ;
Kubota, T ;
Matsufuji, A ;
Maekawa, Y ;
Miyasaka, T .
SCIENCE, 1997, 276 (5317) :1395-1397
[10]   A study on the charge-discharge mechanism of Co3O4 as an anode for the Li ion secondary battery [J].
Kang, YM ;
Song, MS ;
Kim, JH ;
Kim, HS ;
Park, MS ;
Lee, JY ;
Liu, HK ;
Dou, SX .
ELECTROCHIMICA ACTA, 2005, 50 (18) :3667-3673