Core/Shell Ruthenium Halloysite Nanocatalysts for Hydrogenation of Phenol

被引：83

作者：

Vinokurov, Vladimir ^{[1
]}

Glotov, Aleksandr ^{[1
]}

Chudakov, Yaroslav ^{[1
]}

Stavitskaya, Anna ^{[1
]}

Ivanov, Evgenii ^{[1
]}

Gushchin, Pavel ^{[1
]}

Zolotukhina, Anna ^{[2
]}

Maximov, Anton ^{[2
]}

Karakhanov, Eduard ^{[2
]}

Lvov, Yuri ^{[1
,3
]}

机构：

[1] Gubkin Univ, Dept Phys & Colloid Chem, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Petr Chem & Organ Catalysis, Moscow 119991, Russia

[3] Louisiana Tech Univ, Inst Micromfg, Ruston, LA 71272 USA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2017年 / 56卷 / 47期

关键词：

SELECTIVE HYDROGENATION; PHASE HYDROGENATION; SUPPORTED RUTHENIUM; AROMATIC-COMPOUNDS; CATALYTIC-ACTIVITY; RU NANOPARTICLES; MILD CONDITIONS; AQUEOUS-MEDIA; CARBON; NANOTUBES;

D O I：

10.1021/acs.iecr.7b03282

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Halloysite tubular nanoclay was applied as a template for synthesis of ruthenium core shell composite catalysts for the first time; 50 nm diameter ceramic tubular systems with metal seeded interiors were produced. The procedure for the metal deposition and prior halloysite modification had a significant influence on properties of the catalyst and, as a consequence, on its activity in hydrogenation of phenol. Cyclohexanol was the main reaction product, but its yield depended on the substrate conversion and nanoarchitectural composition of the catalysts used. The maximum catalytic activity (turnover frequency, TOF) achieved was 17 282 h(-1) in terms of hydrogen uptake per surface Ru atoms. The substrate selectivity of halloysite-based catalysts was also demonstrated at the comparative hydrogenation of phenol and various cresols.

引用

页码：14043 / 14052

页数：10

共 53 条

[1] Anderson J.R., 1975, Structure of metallic catalysts
[2] Quantitative 1,10-Phenanthroline Catalyst-Poisoning Kinetic Studies of Rh(0) Nanoparticle and Rh4 Cluster Benzene Hydrogenation Catalysts: Estimates of the Poison Kassociation Binding Constants, of the Equivalents of Poison Bound and of the Number of Catalytically Active Sites for Each Catalyst
Bayram, Ercan
Finke, Richard G.
[J]. ACS CATALYSIS, 2012, 2 (09): : 1967 - 1975
[3] REACTIVITY OF CYCLIC AND ACYCLIC OLEFINIC HYDROCARBONS IN ACID-CATALYZED HYDRATION
CHWANG, WK
NOWLAN, VJ
TIDWELL, TT
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (22) : 7233 - 7238
[4] Highly selective hydrogenation of arenes using nanostructured ruthenium catalysts modified with a carbon-nitrogen matrix
Cui, Xinjiang
Surkus, Annette-Enrica
Junge, Kathrin
Topf, Christoph
Radnik, Joerg
Kreyenschulte, Carsten
Beller, Matthias
[J]. NATURE COMMUNICATIONS, 2016, 7
[5] Metal-organic framework (MIL-101) stabilized ruthenium nanoparticles: Highly efficient catalytic material in the phenol hydrogenation
Ertas, Ilknur Efecan
Gulcan, Mehmet
Bulut, Ahmet
Yurderi, Mehmet
Zahmakiran, Mehmet
[J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2016, 226 : 94 - 103
[6] Fibrous Nano-Silica Supported Ruthenium (KCC-1/Ru): A Sustainable Catalyst for the Hydrogenolysis of Alkanes with Good Catalytic Activity and Lifetime
Fihri, Aziz
Bouhrara, Mohamed
Patil, Umesh
Cha, Dongkyu
Saih, Youssef
Polshettiwar, Vivek
[J]. ACS CATALYSIS, 2012, 2 (07): : 1425 - 1431
[7] ESCA STUDIES ON CHARGE-DISTRIBUTION IN SOME DINITROGEN COMPLEXES OF RHENIUM, IRIDIUM, RUTHENIUM, AND OSMIUM
FOLKESSON, B
[J]. ACTA CHEMICA SCANDINAVICA, 1973, 27 (01): : 287 - 302
[8] A novel microwave assisted process for the synthesis of nanostructured ruthenium catalysts active in the hydrogenation of phenol to cyclohexanone
Galletti, Anna Maria Raspolli
Antonetti, Claudia
Longo, Iginio
Capannelli, Gustavo
Venezia, Anna Maria
[J]. APPLIED CATALYSIS A-GENERAL, 2008, 350 (01) : 46 - 52
[9] Behavior of halloysite clay under formamide treatment
Joussein, Emmanuel
Petit, Sabine
Delvaux, Bruno
[J]. APPLIED CLAY SCIENCE, 2007, 35 (1-2) : 17 - 24
[10] Thermo-responsive Ruthenium Dendrimer-based Catalysts for Hydrogenation of the Aromatic Compounds and Phenols
Karakhanov, E.
Maximov, A.
Zolotukhina, A.
Kardasheva, Yu.
Talanova, M.
[J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2016, 26 (06) : 1264 - 1279

← 1 2 3 4 5 6 →