Removal of Chromium (VI) from Water by Using Carbon Nanotubes

被引:0
作者
Atieh, Muataz Ali [1 ]
机构
[1] King Fahd Univ Petr & Minerals, Ctr Excellent Nanotechnol CENT, Dept Chem Engn, Dhahran 31261, Saudi Arabia
来源
PROCEEDINGS OF 2010 INTERNATIONAL CONFERENCE ON ENVIRONMENTAL SCIENCE AND DEVELOPMENT | 2010年
关键词
Carbon Nanotubes; Chromium (VI); Adsorption Isotherm; HEAVY-METAL IONS; ACTIVATED CARBON; LEAD(II) IONS; ADSORPTION; CADMIUM; BIOSORPTION; KINETICS; BIOMASS; PB(II); COPPER;
D O I
暂无
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study was carried out to evaluate the environmental application of carbon nanotubes through the experiment removal of Chromium (VI) from water. The matrix design has been developed in this experimental runs in order to find the optimal condition of the Cr (VI) removal from water. To achieve the objectives of the study, four independent variables including pH, adsorbent dosage, time contact and its agitation speed were carried out to determine the influence of these parameters on the adsorption capacity of the Chromium (VI). Multi wall carbon nanotubes (MWCNTs) were characterized by filed emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) in order to measure the diameter and the length of the adsorbent. The diameter of the carbon nanotubes were varied from 20-40 nm with average diameter at 24 nm and 10 micrometer in length. Adsorption isotherms were used in order to model the adsorption behavior and to calculate the adsorption capacity of the absorbents. The results showed that, carbon nanotubes (CNTs) at pH 7, 150 rpm, and 2 hours achieved 100 % of Cr (VI) removal. These high removal efficiencies were likely attributed to the strong affinity of Chromium (VI) to the physical and chemical properties of the CNTs. The adsorption isotherms plots were well fitted with experimental data.
引用
收藏
页码:147 / 151
页数:5
相关论文
共 22 条
[1]   Enhancement of copper and cadmium adsorption on kaolin by the presence of humic acids [J].
Arias, M ;
Barral, MT ;
Mejuto, JC .
CHEMOSPHERE, 2002, 48 (10) :1081-1088
[2]   Asturian fly ash as a heavy metals removal material [J].
Ayala, J ;
Blanco, F ;
Garcia, P ;
Rodriguez, P ;
Sancho, J .
FUEL, 1998, 77 (11) :1147-1154
[3]   Removal of heavy metal ions from solutions using zeolites. III. Influence of sodium ion concentration in the liquid phase on the kinetics of exchange processes between cadmium ions from solution and sodium ions from zeolite A [J].
Biskup, B ;
Subotic, B .
SEPARATION SCIENCE AND TECHNOLOGY, 2004, 39 (04) :925-940
[4]   Evaluation of the adsorptive capacity of peanut hull pellets for heavy metals in solution [J].
Brown, P ;
Jefcoat, IA ;
Parrish, D ;
Gill, S ;
Graham, E .
ADVANCES IN ENVIRONMENTAL RESEARCH, 2000, 4 (01) :19-29
[5]   Lead metal removal by recycled alum sludge [J].
Chu, W .
WATER RESEARCH, 1999, 33 (13) :3019-3025
[6]   Effect of pH on the adsorption of selected heavy metal ions from concentrated chloride solutions by the chelating resin Dowex M-4195 [J].
Diniz, CV ;
Doyle, FM ;
Ciminelli, VST .
SEPARATION SCIENCE AND TECHNOLOGY, 2002, 37 (14) :3169-3185
[7]   Effect of oxidation of activated carbon on its enrichment efficiency of metal ions: Comparison with oxidized and non-oxidized multi-walled carbon nanotubes [J].
El-Sheikh, Amjad H. .
TALANTA, 2008, 75 (01) :127-134
[8]   Carbon nanotubes [J].
Haddon, RC .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (12) :997-997
[9]   The sorption of lead(II) ions on peat [J].
Ho, YS ;
McKay, G .
WATER RESEARCH, 1999, 33 (02) :578-584
[10]   Adsorption behavior of heavy metal ions by carbon nanotubes grown on microsized Al2O3 particles [J].
Hsieh, Shu-Huei ;
Horng, Jao-Jia .
JOURNAL OF UNIVERSITY OF SCIENCE AND TECHNOLOGY BEIJING, 2007, 14 (01) :77-84