Very fast enantioseparation in high-performance liquid chromatography using cellulose tris(3,5-dimethylphenylcarbamate) coated on monolithic silica support

被引：54

作者：

Chankvetadze, B

Yamamoto, C

Okamoto, Y ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan

[2] Tbilisi State Univ, Sch Chem, Mol Recognit & Separat Sci Lab, GE-380028 Tbilisi, Georgia

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 09期

关键词：

D O I：

10.1246/cl.2003.850

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of the high chiral recognition ability of cellulose tris(3,5-dimethylphenylcarbamate) (CDMPC) with the favorable dynamic properties of a silica-based monolithic chromatographic support allowed the baseline enantioseparation of 2,2,2-trifluoro-1-(9-anthryl)ethanol with the retention times of 7.2 and 18.5 s for the first and second eluted enantiomers, respectively. The separation was accomplished in 30 s which may be the shortest time in which baseline HPLC enantioseparations have been reported.

引用

页码：850 / 851

页数：2

共 11 条

[1] Fast enantioseparations of basic analytes by high-performance liquid chromatography using cellulose tris(3,5-dimethylphenylcarbamate)-coated zirconia stationary phases [J].