Independent parallel pyrolysis kinetics of extracted proteins and lipids as well as model carbohydrates in microalgae

被引：47

作者：

Aniza, Ria ^{[1
,2
]}

Chen, Wei-Hsin ^{[2
,3
,4
]}

Lin, Yu-Ying ^{[2
]}

Tran, Khanh-Quang ^{[5
]}

Chang, Jo-Shu ^{[3
,6
,7
]}

Lam, Su Shiung ^{[8
,9
]}

Park, Young-Kwon ^{[10
]}

Kwon, Eilhann E. ^{[11
]}

Tabatabaei, Meisam ^{[8
,9
,12
,13
]}

机构：

[1] Natl Cheng Kung Univ, Int Doctoral Degree Program Energy Engn, Tainan 701, Taiwan

[2] Natl Cheng Kung Univ, Dept Aeronaut & Astronaut, Tainan 701, Taiwan

[3] Tunghai Univ, Res Ctr Smart Sustainable Circular Econ, Taichung 407, Taiwan

[4] Natl Chin Yi Univ Technol, Dept Mech Engn, Taichung 411, Taiwan

[5] Norwegian Univ Sci & Technol, Dept Energy & Proc Engn, NO-7491 Trondheim, Norway

[6] Natl Cheng Kung Univ, Dept Chem Engn, Tainan 701, Taiwan

[7] Tunghai Univ, Dept Chem & Mat Engn, Taichung 411, Taiwan

[8] Univ Malaysia Terengganu, Higher Inst Ctr Excellence HICoE, Inst Trop Aquaculture & Fisheries AKUATROP, Kuala Nerus 21030, Malaysia

[9] Henan Agr Univ, Henan Prov Forest Resources Sustainable Dev & Hig, Sch Forestry, Zhengzhou 450002, Peoples R China

[10] Univ Seoul, Sch Environm Engn, Seoul 02504, South Korea

[11] Sejong Univ, Dept Environm & Energy, Seoul 05006, South Korea

[12] Biofuel Res Team BRTeam, Terengganu, Malaysia

[13] Agr Res Educ & Extens Org AREEO, Microbial Biotechnol Dept, Agr Biotechnol Res Inst Iran ABRII, Karaj, Iran

来源：

APPLIED ENERGY | 2021年 / 300卷

关键词：

Microalgae pyrolysis; Thermogravimetric analysis (TGA); Protein; lipid; and carbohydrates; Independent parallel reaction (IPR); Particle swarm optimization (PSO); Synergistic and antagonistic effects; ACTIVATION-ENERGY MODEL; THERMOGRAVIMETRIC ANALYSIS; CHLORELLA-VULGARIS; CO-PYROLYSIS; CATALYTIC PYROLYSIS; THERMAL-BEHAVIOR; BIOMASS; COMBUSTION; STARCH; OPTIMIZATION;

D O I：

10.1016/j.apenergy.2021.117372

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Microalgae offer unique potentials for developing advanced biorefineries, including third-generation biofuel production, wastewater treatment, and animal and aquaculture feed production. The thermodegradation of protein, lipid, and carbohydrates plays a vital role in the thermochemical conversion of microalgae for biofuel production. This work aims to investigate the kinetics and the interaction of extracted protein and lipid as well as model carbohydrates from microalgae to assist the development of microalgae conversion techniques, which have not been studied so far. Thermogravimetric analysis is integrated with an independent parallel reaction (IPR) and particle swarm optimization (PSO) method to explore the pyrolysis kinetics of three constituents (protein, lipid, and carbohydrates). The calorific values of the three constituents show that protein (5.33 MJ.kg(-1)) is not a suitable biofuel feedstock. In contrast, lipid (34.22 MJ.kg(-1)) and carbohydrates (15.37-15.84 MJ.kg(-1)) are considered as potential feedstocks for liquid and solid biofuel production, respectively. The pyrolysis processes suggest that the thermodegradation extent follows the order of carbohydrates > protein > lipid. The application of the IPR-PSO method on the pyrolysis kinetics of microalgae in three pseudo-components obtains a high fit quality (>96%) for all cases, indicating that the method is suitable to predict the kinetics parameters of the three constituents of microalgae. The effect analysis reveals that the synergistic effect accounts for about 50% of the total mass of the thermodegradation process of model carbohydrates, occuring at 200-320 degrees C. Meanwhile, the theoretical and experimental thermogravimetric analysis curve of combination of the three constituents suggests that there are four regions detected, including strong synergistic effect, weak antagonistic effect, weak synergistic effect, and strong antagonistic effect, respectively.

引用

页数：14

共 90 条

[11] Thermogravimetric analysis of microalgae combustion under different oxygen supply concentrations [J].