Synthesis of functionalized resorcinols by rhodium-catalyzed [5+1] cycloaddition reaction of 3-acyloxy-1,4-enynes with CO

被引：56

作者：

Brancour, Celia ^{[2
]}

Fukuyama, Takahide ^{[1
]}

Ohta, Yuko ^{[1
]}

Ryu, Ilhyong ^{[1
]}

Dhimane, Anne-Lise ^{[2
]}

Fensterbank, Louis ^{[2
]}

Malacria, Max ^{[2
]}

机构：

[1] Osaka Prefecture Univ, Grad Sch Sci, Dept Chem, Osaka 5998531, Japan

[2] Univ Paris 06, Inst Parisien Chim Mol, UMR CNRS 7201, FR 2769, F-75005 Paris, France

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 30期

关键词：

KETENE LIGAND; COMPLEXES; CARBONYLATION; CYCLIZATION; ACETATES; CYCLOISOMERIZATION; 2-CYCLOPENTENONES; N-ENYNES; CHEMISTRY; EFFICIENT;

D O I：

10.1039/c0cc00747a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel [5+1] type carbonylative cycloaddition reaction has been developed using a Rh complex as catalyst. This reaction can convert readily available 3-acyloxy-1,4-enynes and CO to a wide range of functionalized resorcinols in good yields. A mechanism involving Rh-catalyzed cyclocarbonylation of 3-acyloxy-1,4-enynes accompanied by a 1,2-acyloxy shift is proposed for the present [5+1] type cycloaddition reaction.

引用

页码：5470 / 5472

页数：3

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