Surface modification of PET with ethoxylated hexylaminoanthraquinones by exhaustion method

被引:3
作者
Cui, YZ [1 ]
Yoon, N [1 ]
机构
[1] Kyungpook Natl Univ, Dept Dyeing & Finishing, Taegu 702701, South Korea
关键词
poly(ethylene terephthalate); surface modification; exhaustion; cloud point; water contact angle; XPS;
D O I
10.1016/S0143-7208(03)00063-9
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Surface modification of poly(ethylene terephthalate) (PET) films by treatment with ethoxylated hexylaminoanthraquinones synthesized by the reaction of I-aminoanthraquinone with poly(ethylene glycol)s via hexamethylene spacer was investigated. The ethoxylated hexylaminoanthraquinones showed nonionic surfactant nature with definite cloud points, and were successfully applied on to PET by usual exhaustion method as in dyeing. The depth profile of XPS showed that the ethoxylated hexylaminoanthraquinones are adsorbed only onto the extreme surface of PET. Water contact angle was decreased by the adsorption. These results indicate that the ethoxylated hexylaminoanthraquinones anchor on PET surface with ethoxylated hydrophilic moiety outwards. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:121 / 125
页数:5
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