Novel Rhenium Nitrides

被引：147

作者：

Friedrich, Alexandra ^{[1
]}

Winkler, Bjoern ^{[1
]}

Bayarjargal, Lkhamsuren ^{[1
]}

Morgenroth, Wolfgang ^{[1
]}

Juarez-Arellano, Erick A. ^{[2
]}

Milman, Victor ^{[3
]}

Refson, Keith ^{[4
]}

Kunz, Martin ^{[5
]}

Chen, Kai ^{[5
]}

机构：

[1] Goethe Univ Frankfurt, D-60438 Frankfurt, Germany

[2] Univ Papaloapan, Tuxtepec 68301, Mexico

[3] Accelrys, Cambridge CB4 0WN, England

[4] Rutherford Appleton Lab, Didcot OX11 0QX, Oxon, England

[5] Univ Calif Berkeley, Lawrence Berkeley Lab, Adv Light Source, Berkeley, CA 94720 USA

来源：

PHYSICAL REVIEW LETTERS | 2010年 / 105卷 / 08期

关键词：

HIGH-TEMPERATURE SYNTHESIS; PULSED-LASER DEPOSITION; HIGH-PRESSURE; CARBON; PLATINUM; CARBIDE; DIAMOND; FILMS;

D O I：

10.1103/PhysRevLett.105.085504

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We report the synthesis, structure, and properties of novel bulk rhenium nitrides, hexagonal Re(2)N, and Re(3)N. Both phases have very high bulk moduli of >400 GPa, similar to the most incompressible binary transition-metal (TM) carbides and nitrides found to date. However, in contrast to other incompressible TM carbides and nitrides, Re(3)N is better placed for potential technological applications, as it can be formed at relatively moderate pressures (13-16 GPa) and temperatures (1600-2400 K).

引用

页数：4

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