Synthesis and crystal structure of [CuCl(phen)2]3H3V10O28 • 7H2O

被引：15
作者：
Rakovsky, E
Joniaková, D
Gyepes, R
Schwendt, P
Micka, Z
机构：
[1] Comenius Univ, Fac Nat Sci, Dept Inorgan Chem, Bratislava 84215, Slovakia
[2] Charles Univ Prague, Fac Nat Sci, Dept Inorgan Chem, Prague 12800, Czech Republic
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 2005年 / 40卷 / 07期
关键词：
trihydrogendecavanadate; heptahydrate; X-ray diffraction; structure analysis; bond-length/bond-number calculation;
D O I：
10.1002/crat.200410415
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The new compound, [CuCl(phen)(2)](3)H3V10O28 center dot 7H(2)O, was prepared by reaction of an aqueous KVO3 solution (pH 3) with an aqueous solution of CuSO4 center dot 5 H2O in which 1,10-phenanthroline (phen) and KCl were added. The crystal structure of the compound was determined, and the proton position in H3V10O283- were calculated by the bond length/bond number method and also determined from difference electron density map. The protons are bound to colinearly arranged mu-OV2 and mu-OV3 groups which is the common protonation type in trihydrogen decavanadates. The structure crystallizes in P1 space group symmetry. (c) 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：719 / 722
页数：4
相关论文
共 50 条
[31]   Crystal growth and structure of (2-C2H5C6H4NH3)2H2P2O7 [J].
Akriche, S ;
Rzaigui, M .
MATERIALS RESEARCH BULLETIN, 2001, 36 (1-2) :375-382
[32]   Influence of the Organic Species and Oxoanion in the Synthesis of two Uranyl Sulfate Hydrates, (H3O)2[(UO2)2(SO4)3-(H2O)]•7H2O and (H3O)2[(UO2)2(SO4)3(H2O)]•4H2O, and a Uranyl Selenate-Selenite [C5H6N][(UO2)(SeO4)(HSeO3)] [J].
Jouffret, Laurent J. ;
Wylie, Ernest M. ;
Burns, Peter C. .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (11) :1796-1803
[33]   New Borate-citrate: Synthesis, Structure, and Properties of Sr[B(C6H5O7)2](H2O)4•3H2O [J].
Wu, Hongping ;
Pan, Shilie ;
Jia, Dianzeng ;
Yu, Hongwei ;
Chen, Zhaohui .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (05) :856-860
[34]   Crystal Structure, Synthesis, and Properties of tri-Calcium di-Citrate tetra-Hydrate [Ca3(C6H5O7)2(H2O)2]•2H2O [J].
Herdtweck, Eberhardt ;
Kornprobst, Tobias ;
Sieber, Roland ;
Straver, Leo ;
Plank, Johann .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (06) :655-659
[35]   Synthesis and characterization of a new cyclohexaphosphate, (C10H13NH3)4(H3O)2(P6O18)•3(H2O) [J].
Amri, O. ;
Abid, S. ;
Rzaigui, M. .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2008, 183 (08) :1984-1993
[36]   Crystal Structure of Molybdate Pyridine Copper: C10H10N2O10Cu3Mo2 [J].
Liu, Hai-Xing ;
Wang, Lin-Tong ;
Jian, Fang-Fang ;
Wang, Jing ;
Liu, Qing ;
Ye, Kai-Qi ;
Zeng, Guang ;
Tai, Xi-Shi .
ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (14) :8219-8220
[37]   Synthesis and crystal structure of the coordination polymer [{Li(H2O)3}2(C36H36N24O12)]Cl2•6H2O [J].
Kovalenko, E. A. ;
Samsonenko, D. G. ;
Fedin, V. P. .
RUSSIAN CHEMICAL BULLETIN, 2018, 67 (01) :127-130
[38]   Synthesis and crystal structure of the coordination polymer [{Li(H2O)3}2(C36H36N24O12)]Cl2•6H2O [J].
E. A. Kovalenko ;
D. G. Samsonenko ;
V. P. Fedin .
Russian Chemical Bulletin, 2018, 67 :127-130
[39]   Synthesis, Crystal Structure and Thermal Decomposition of [HGdP2O7•2 H2O]•NH3 Electric properties of HGdP2O7 and Gd2P4O13 [J].
Zrelli-Annabi, R. ;
Chehimi-Moumen, F. ;
Moutaabbid, H. ;
Kurakevych, O. ;
Le Godec, Y. ;
Hassen-Chehimi, D. Ben ;
Trabelsi-Ayadi, M. .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2019, 194 (1-2) :5-12
[40]   Synthesis and crystal structure of Cs2[(UO2)2(C2O4)3] and Cs2[UO2(C3H2O4)2] • H2O [J].
Serezhkina, L. B. ;
Peresypkina, E. V. ;
Medvedkov, Ya A. ;
Virovets, A. V. ;
Serezhkin, V. N. .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (12) :1465-1469
12345