Synthesis and crystal structure of [CuCl(phen)2]3H3V10O28 • 7H2O

被引：15
作者：
Rakovsky, E
Joniaková, D
Gyepes, R
Schwendt, P
Micka, Z
机构：
[1] Comenius Univ, Fac Nat Sci, Dept Inorgan Chem, Bratislava 84215, Slovakia
[2] Charles Univ Prague, Fac Nat Sci, Dept Inorgan Chem, Prague 12800, Czech Republic
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 2005年 / 40卷 / 07期
关键词：
trihydrogendecavanadate; heptahydrate; X-ray diffraction; structure analysis; bond-length/bond-number calculation;
D O I：
10.1002/crat.200410415
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The new compound, [CuCl(phen)(2)](3)H3V10O28 center dot 7H(2)O, was prepared by reaction of an aqueous KVO3 solution (pH 3) with an aqueous solution of CuSO4 center dot 5 H2O in which 1,10-phenanthroline (phen) and KCl were added. The crystal structure of the compound was determined, and the proton position in H3V10O283- were calculated by the bond length/bond number method and also determined from difference electron density map. The protons are bound to colinearly arranged mu-OV2 and mu-OV3 groups which is the common protonation type in trihydrogen decavanadates. The structure crystallizes in P1 space group symmetry. (c) 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：719 / 722
页数：4
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