A new luminescent complex constructed by oxomolybdate and 3,5-di(4H-1,2,4-triazol-4-yl)benzoic acid via Mo-N bonds

被引:11
作者
Liu, Bin [1 ]
Yu, Ying-Hui [1 ]
Jiang, Wen-Hong [1 ]
Hou, Guang-Feng [1 ,2 ]
Gao, Jin-Sheng [1 ,2 ]
机构
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
[2] Heilongjiang Univ, Engn Res Ctr Pesticide, Harbin 150080, Peoples R China
基金
中国国家自然科学基金;
关键词
Coordination polymers; Triazole; Oxomolybdate; Luminescent; Electrochemical; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; MOLYBDENUM(VI) COMPLEX; OLEFIN EPOXIDATION; LIGAND; PHOTOLUMINESCENCE; OCTAMOLYBDATE; MAGNETISM; MOLYBDATE; FAMILY;
D O I
10.1016/j.inoche.2015.01.034
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new complex namely, [(Mo2O6)L]center dot CH3OH center dot 3H(2)O (1), based on oxomolybdate and 3,5-di(4H-1,2,4-triazol-4-yl) benzoic acid (L) was synthesized under hydrothermal condition, which shows a new three-dimensional supramolecular framework with unreported topological structure. In addition, the luminescent and electrochemical behaviors of complex 1 were investigated. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:12 / 15
页数:4
相关论文
共 31 条
[1]   A dinuclear oxo-bridged molybdenum(VI) complex containing a bidentate pyrazolylpyridine ligand: Structure, characterization and catalytic performance for olefin epoxidation [J].
Amarante, Tatiana R. ;
Gomes, Ana C. ;
Neves, Patricia ;
Almeida Paz, Filipe A. ;
Valente, Anabela A. ;
Pillinger, Martyn ;
Goncalves, Isabel S. .
INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 32 :59-63
[2]   A dinuclear oxomolybdenum(VI) complex, [Mo2O6(4,4′-di-tert-butyl-2,2′-bipyridine)2], displaying the {MoO2(μ-O)2MoO2}0 core, and its use as a catalyst in olefin epoxidation [J].
Amarante, Tatiana R. ;
Neves, Patricia ;
Almeida Paz, Filipe A. ;
Pillinger, Martyn ;
Valente, Anabela A. ;
Goncalves, Isabel S. .
INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 20 :147-152
[3]   An Octanuclear Molybdenum(VI) Complex Containing Coordinative ly Bound 4,4′-di-tert-Butyl-2,2′-Bipyridine, [Mo8O22(OH)4(di-tBu-bipy)4]: Synthesis, Structure, and Catalytic Epoxidation of Bio-Derived Olefins [J].
Amarante, Tatiana R. ;
Neves, Patricia ;
Tome, Catia ;
Abrantes, Marta ;
Valente, Anabela A. ;
Almeida Paz, Filipe A. ;
Pillinger, Martyn ;
Goncalves, Isabel S. .
INORGANIC CHEMISTRY, 2012, 51 (06) :3666-3676
[4]   Coordination polymers, metal-organic frameworks and the need for terminology guidelines [J].
Batten, Stuart R. ;
Champness, Neil R. ;
Chen, Xiao-Ming ;
Garcia-Martinez, Javier ;
Kitagawa, Susumu ;
Ohrstrom, Lars ;
O'Keeffe, Michael ;
Suh, Myunghyun Paik ;
Reedijk, Jan .
CRYSTENGCOMM, 2012, 14 (09) :3001-3004
[5]   A new synthetic approach to functionalize oxomolybdenum complexes [J].
Chen, Baokuan ;
Lin, Zhengguo ;
Wang, Bo ;
Feng, Xiao ;
Fan, Linyuan ;
Yang, Song ;
Huang, Xianqiang ;
Hu, Changwen .
CRYSTENGCOMM, 2013, 15 (37) :7410-7413
[6]   Engineering Metal Organic Frameworks for Heterogeneous Catalysis [J].
Corma, A. ;
Garcia, H. ;
Llabres i Xamena, F. X. L. I. .
CHEMICAL REVIEWS, 2010, 110 (08) :4606-4655
[7]   Synthesis, characterization, and photochromic properties of hybrid organic-inorganic materials based on molybdate, DABCO, and piperazine [J].
Coue, Violaine ;
Dessapt, Remi ;
Bujoli-Doeuff, Martine ;
Evain, Michel ;
Jobic, Stephane .
INORGANIC CHEMISTRY, 2007, 46 (07) :2824-2835
[8]   Hydrogen storage in a microporous metal-organic framework with exposed Mn2+ coordination sites [J].
Dinca, Mircea ;
Dailly, Anne ;
Liu, Yun ;
Brown, Craig M. ;
Neumann, Dan. A. ;
Long, Jeffrey R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) :16876-16883
[9]   Synthesis, structure, and reactivity of a new mononuclear molybdenum(VI) complex resembling the active center of molybdenum oxotransferases [J].
Dinda, R ;
Sengupta, P ;
Ghosh, S ;
Sheldrick, WS .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (02) :363-369
[10]   Ligand influences on the structures of molybdenum oxide networks [J].
Hagrman, PJ ;
LaDuca, RL ;
Koo, HJ ;
Rarig, R ;
Haushalter, RC ;
Whangbo, MH ;
Zubieta, J .
INORGANIC CHEMISTRY, 2000, 39 (19) :4311-4317