Viscosities of fatty mixtures:: Experimental data and prediction

被引:20
作者
Goncalves, Cintia B.
Ceriani, Roberta
Rabelo, Juliana
Maffia, Maria Cristina
Meirelles, Antonio J. A.
机构
[1] Univ Sao Paulo, Dept Food Engn, BR-13625 Pirassununga, SP, Brazil
[2] Univ Estadual Campinas, UNICAMP, Dept Food Engn, BR-13083970 Campinas, SP, Brazil
[3] Univ Fed Vicosa, Dept Food Technol, BR-36570 Vicosa, MG, Brazil
关键词
D O I
10.1021/je700293s
中图分类号
O414.1 [热力学];
学科分类号
摘要
Viscosity data of fatty compounds and their mixtures are important for designing equipment for the oil industry, including edible, as some vegetable oils, and nonedible purposes, as biodiesel. To expand the data bank gathered from the literature, the present work reports viscosity data of fatty mixtures found in the oil and fat industry, such as mixtures of fatty acids, methyl esters, and triacylglycerols, over a large range of temperatures. Viscosities of these fatty mixtures as well as viscosity data taken from the literature were predicted by known methods, such as the modified Kay's rule, the Kendall and Moore model, and GC-UNIMOD. In general, the three models presented a good representation of the kinematic viscosity of fatty mixtures. For the majority of cases (or 77.1%), the average relative deviations (ARD) obtained were not higher than 10%.
引用
收藏
页码:2000 / 2006
页数:7
相关论文
共 36 条
[21]   The viscosity of liquids. II. The viscosity-composition curve for ideal liquid mixtures. [J].
Kendall, J ;
Monroe, KP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1917, 39 :1787-1802
[22]   Kinematic viscosity of biodiesel fuel components and related compounds. Influence of compound structure and comparison to petrodiesel fuel components [J].
Knothe, G ;
Steidley, KR .
FUEL, 2005, 84 (09) :1059-1065
[23]   An empirical approach in predicting biodiesel viscosity at various temperatures [J].
Krisnangkura, K ;
Yimsuwan, T ;
Pairintra, R .
FUEL, 2006, 85 (01) :107-113
[24]  
Lide D. R., 1994, Handbook of Chemistry and Physics, V74th
[25]   VISCOSITIES OF LONG-CHAIN N-ALCOHOLS FROM 15-DEGREES-C TO 80-DEGREES-C [J].
LIEW, KY ;
SENG, CE ;
NG, BH .
JOURNAL OF SOLUTION CHEMISTRY, 1993, 22 (11) :1033-1040
[26]   VISCOSITIES OF SOME LONG-CHAIN FATTY-ACIDS AND THEIR RELATIONSHIP WITH CHAINLENGTH [J].
LIEW, KY ;
SENG, CE ;
LAU, EK .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1991, 68 (07) :488-492
[27]   VISCOSITIES AND DENSITIES OF THE METHYL-ESTERS OF SOME N-ALKANOIC ACIDS [J].
LIEW, KY ;
SENG, CE ;
OH, LL .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1992, 69 (02) :155-158
[28]  
MARKLEY KS, 1960, FATTY ACIDS CHEM PHY, P222
[29]   VISCOSITIES OF VEGETABLE-OILS AND FATTY-ACIDS [J].
NOUREDDINI, H ;
TEOH, BC ;
CLEMENTS, LD .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1992, 69 (12) :1189-1191
[30]   Viscosity prediction for fatty systems [J].
Rabelo, J ;
Batista, E ;
Cavaleri, FW ;
Meirelles, AJA .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2000, 77 (12) :1255-1261