Viscosities of fatty mixtures:: Experimental data and prediction

被引:20
作者
Goncalves, Cintia B.
Ceriani, Roberta
Rabelo, Juliana
Maffia, Maria Cristina
Meirelles, Antonio J. A.
机构
[1] Univ Sao Paulo, Dept Food Engn, BR-13625 Pirassununga, SP, Brazil
[2] Univ Estadual Campinas, UNICAMP, Dept Food Engn, BR-13083970 Campinas, SP, Brazil
[3] Univ Fed Vicosa, Dept Food Technol, BR-36570 Vicosa, MG, Brazil
关键词
D O I
10.1021/je700293s
中图分类号
O414.1 [热力学];
学科分类号
摘要
Viscosity data of fatty compounds and their mixtures are important for designing equipment for the oil industry, including edible, as some vegetable oils, and nonedible purposes, as biodiesel. To expand the data bank gathered from the literature, the present work reports viscosity data of fatty mixtures found in the oil and fat industry, such as mixtures of fatty acids, methyl esters, and triacylglycerols, over a large range of temperatures. Viscosities of these fatty mixtures as well as viscosity data taken from the literature were predicted by known methods, such as the modified Kay's rule, the Kendall and Moore model, and GC-UNIMOD. In general, the three models presented a good representation of the kinematic viscosity of fatty mixtures. For the majority of cases (or 77.1%), the average relative deviations (ARD) obtained were not higher than 10%.
引用
收藏
页码:2000 / 2006
页数:7
相关论文
共 36 条
[1]   Predicting the viscosity of biodiesel fuels from their fatty acid ester composition [J].
Allen, CAW ;
Watts, KC ;
Ackman, RG ;
Pegg, MJ .
FUEL, 1999, 78 (11) :1319-1326
[2]  
[Anonymous], 1979, Bailey's industrial oil and fat products, DOI DOI 10.1016/S0015-6264(80)80034-4
[3]   Viscosity estimation of triacylglycerols and of some vegetable oils, based on their triacylglycerol composition [J].
Azian, MN ;
Kamal, AAM ;
Panau, F ;
Ten, WK .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2001, 78 (10) :1001-1005
[4]   DEPENDENCE OF VISCOSITIES OF SOME ORGANIC ALIPHATIC-ACIDS ON TEMPERATURE AND MOLAR VOLUME [J].
BERCHIESI, G ;
LEONESI, D ;
CINGOLANI, A .
JOURNAL OF THERMAL ANALYSIS, 1976, 9 (02) :171-179
[5]   ESTERS OF NATURALLY OCCURRING FATTY ACIDS - PHYSICAL PROPERTIES OF METHYL, PROPYL, AND ISOPROPYL ESTERS OF C-6 TO C-18 SATURATED FATTY ACIDS [J].
BONHORST, CW ;
ALTHOUSE, PM ;
TRIEBOLD, HO .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1948, 40 (12) :2379-2384
[6]  
BROCKMANN R, 1987, ULLMANNS ENCY IND CH, P245
[7]   GROUP-CONTRIBUTION VISCOSITY PREDICTIONS OF LIQUID-MIXTURES USING UNIFAC-VLE PARAMETERS [J].
CAO, WH ;
KNUDSEN, K ;
FREDENSLUND, A ;
RASMUSSEN, P .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (09) :2088-2092
[8]   Viscosities of binary and ternary mixtures of hexadecanoic, octadecanoic, and cis-9-octadecenoic acids [J].
Cedeño, FO ;
Prieto, MM ;
Huidobro, JA .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2000, 45 (02) :219-224
[9]   Simulation of continuous deodorizers: Effects on product streams [J].
Ceriani, R ;
Meirelles, AJA .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2004, 81 (11) :1059-1069
[10]   Group contribution model for predicting viscosity of fatty compounds [J].
Ceriani, Roberta ;
Goncalves, Cintia B. ;
Rabelo, Juliana ;
Caruso, Marcel ;
Cunha, Ana C. C. ;
Cavaleri, Flavio W. ;
Batista, Eduardo A. C. ;
Meirelles, Antonio J. A. .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (03) :965-972