BaBiBO4, a novel non-centrosymmetric borate oxide

被引：71
作者：
Barbier, J
Penin, N
Denoyer, A
Cranswick, LMD
机构：
[1] McMaster Univ, Dept Chem, Hamilton, ON L8S 4M1, Canada
[2] Natl Res Council Canada, Chalk River Labs, Neutron Program Mat Res, Chalk River, ON K0J 1J0, Canada
来源：
SOLID STATE SCIENCES | 2005年 / 7卷 / 09期
基金：
加拿大自然科学与工程研究理事会;
关键词：
BaBiBO4; borate; crystal structure; NLO properties;
D O I：
10.1016/j.solidstatesciences.2004.11.031
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
BaBiBO4, or BaBi(BO3)O, is a novel borate oxide which has been synthesized by solid-state reaction at temperatures below 650 degrees C and 1 atm pressure. Its crystal structure has been determined from powder X-ray diffraction data and refined from powder neutron diffraction data (non-centrosymmetric Pna2(1) space group, a = 8.5817(7), b = 9.6802(7), c = 5.1505(4) angstrom, Z = 4). The structure is built of [001] chains of edge-sharing BO3 and BiO5 groups interleaved with Ba2+ cations. The measurement of the nonlinear optical properties of a powder sample by the Kurtz-Perry method yielded an efficiency for second-harmonic generation equal to five times that of KH2PO4. (c) 2005 Elsevier SAS. All rights reserved.
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页码：1055 / 1061
页数：7
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