Effects of Nanosized Polystyrene and Polystyrene-Encapsulated Nanosilica on Physical Properties of Natural Rubber/Styrene Butadiene Rubber Nanocomposites

被引:13
作者
Boonmahitthisud, Anyaporn [1 ,2 ]
Chuayjuljit, Saowaroj [1 ,2 ]
机构
[1] Chulalongkorn Univ, Fac Sci, Dept Mat Sci, Bangkok 10330, Thailand
[2] Chulalongkorn Univ, Ctr Petr Petrochem & Adv Mat, Bangkok 10330, Thailand
关键词
Nanocomposites; Nanosized polystyrene; Natural rubber; Polystyrene-encapsulated nanosilica; Styrene butadiene rubber; MECHANICAL-PROPERTIES; STYRENE; BLENDS; LATEX; SBR; MORPHOLOGY; BEHAVIOR; REINFORCEMENT; NANOPARTICLES; POLYMER;
D O I
10.1080/03602559.2011.639330
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Natural rubber (NR)/styrene butadiene rubber (SBR) nanocomposites have been prepared with nanosized polystyrene (nPS) and polystyrene-encapsulated nanosilica (PS-nSiO(2)) through latex compounding. The nPS and PS-nSiO(2) were synthesized by differential microemulsion polymerization. 80/20 NR/SBR blend was filled with various loadings of nPS and PS-nSiO(2) (1, 3, 5 and 7 phr). The influence of nanofillers on the tensile properties, dynamic mechanical properties and thermal stability of the resulting nanocomposites was quantified. The results showed the improvement in the tensile strength, modulus and thermal stability by the appropriate amount of nPS and PS-nSiO(2) in the nanocomposites, whilst the elongation at break slightly deteriorated.
引用
收藏
页码:311 / 316
页数:6
相关论文
共 30 条
[1]   Natural Rubber-Carbon Nanotube Composites through Latex Compounding [J].
Anand, Anoop K. ;
Jose, Sunil T. ;
Alex, Rosamma ;
Joseph, Rani .
INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS, 2010, 59 (01) :33-44
[2]  
[Anonymous], INT J POLYM MAT
[3]   Properties of aluminium and zinc-filled natural rubber composites [J].
Anuar, J. ;
Mariatti, M. ;
Ismail, H. .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2007, 46 (06) :667-674
[4]   Enhanced Tensile and Dynamic Mechanical Properties of Thermoplastic Natural Rubber Nanocomposites [J].
Azlina, H. Noor ;
Sahrim, H. A. ;
Rozaidi, R. .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2011, 50 (13) :1383-1387
[5]  
Cai HH, 2003, J APPL POLYM SCI, V87, P982, DOI [10.1002/app.11410, 10.1002/app.11045]
[6]   Radiation-induced vulcanisation of natural rubber latex in presence of styrene-butadiene rubber latex [J].
Chaudhari, CV ;
Bhardwaj, YK ;
Patil, ND ;
Dubey, KA ;
Kumar, V ;
Sabharwal, S .
RADIATION PHYSICS AND CHEMISTRY, 2005, 72 (05) :613-618
[7]   Natural Rubber Blended with Polystyrene Nanoparticles Prepared by Differential Microemulsion Polymerization [J].
Chuayjuljit, Saowaroj ;
Boonmahithisud, Anyaporn .
JOURNAL OF ELASTOMERS AND PLASTICS, 2010, 42 (04) :375-387
[8]   Natural rubber nanocomposites using polystyrene-encapsulated nanosilica prepared by differential microemulsion polymerization [J].
Chuayjuljit, Saowaroj ;
Boonmahitthisud, Anyaporn .
APPLIED SURFACE SCIENCE, 2010, 256 (23) :7211-7216
[9]   Modification of acrylonitrile-butadiene rubber/natural rubber (NBR/NR) blends with tetrachloro plithalic anhydride [J].
El-Nashar, DE ;
Abd-El-Messieh, SL ;
Eid, MAM .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2004, 43 (03) :671-693
[10]  
George SC, 2000, J APPL POLYM SCI, V78, P1280, DOI 10.1002/1097-4628(20001107)78:6<1280::AID-APP150>3.0.CO