Benzenesulfonamide-thiazole system bearing an azide group: Synthesis and evaluation of its optical nonlinear responses

被引：22

作者：

Al-Hujaj, Hamsa Hussein ^{[1
]}

Hassan, Qusay M. A. ^{[2
]}

Almashal, Faeza Abdulkareem ^{[1
]}

Sultan, H. A. ^{[2
]}

Dhumad, Adil Muala ^{[1
]}

Jassem, Ahmed Majeed ^{[1
]}

Emshary, C. A. ^{[2
]}

机构：

[1] Univ Basrah, Coll Educ Pure Sci, Dept Chem, Basrah 61001, Iraq

[2] Univ Basrah, Coll Educ Pure Sci, Dept Phys, Basrah 61001, Iraq

来源：

OPTIK | 2022年 / 265卷

关键词：

Azide; Benzenesulfonamide-thiazole; Optical nonlinearities; Diffraction ring patterns; Z-scan; SPECTRAL CHARACTERISTICS; LIMITING PROPERTIES; DYE; BEHAVIOR;

D O I：

10.1016/j.ijleo.2022.169477

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Objective: The current study aims to find a material that has high nonlinear optical properties to be used in photonic applications. Methods: The synthesis and characterization of benzenesulfonamide-thiazole compound containing an azide group: 4-azido-N-(thiazol-2-yl) benzenesulfonamide 5 (C9H7N5O2S2) via four steps are described. H-1 and C-13 NMR, FTIR, and mass spectmscopies are used in the study of the synthesized compound 5, together with UV-visible analysis to determine its linear absorption coefficient.The density function theory calculations are used to obtain the compound 5 optimized structure. Results: The optical nonlinear properties of the compound 5 are studied using continuous wave laser beam via the determination of its nonlinear refractive index and the coefficient of nonlinear absorption based on the diffraction ring patterns and the Z-scan respectively. All-optical switching property is tested using two continuous wave laser beams viz., 473 nm and 532 nm.

引用

页数：16

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