Compatibilizing effect of maleic anhydride grafted styrene-ethylene-butylene-styrene (MAH-g-SEBS) on the polypropylene and wood fiber composites

被引:11
作者
Guo, C. G. [1 ]
Wang, Q. W. [1 ]
机构
[1] NE Forestry Univ, Minist Educ, Key Lab Biobased Mat Sci & Technol, Harbin 150040, Peoples R China
关键词
polypropylene; wood fiber; MAH-g-SEBS; compatibilizer; DMA;
D O I
10.1177/0731684407079345
中图分类号
TB33 [复合材料];
学科分类号
摘要
Polypropylene (PP) and wood fiber (WF) composites (PP/WF) were compatibilized by maleic anhydride grafted Styrene-Ethylene-Butylene-Styrene (MAH-g-SEBS). The blending was performed on a twin-screw extrusion, followed by an injection molding. The torque rheology, dynamic mechanical analysis (DMA), thermal analysis (DSC), mechanical properties, as well as the morphology of the composites, were investigated and discussed. Rheology and DMA results showed that MAH-g-SEBS is an effective compatibilizer for PP/WF composites. Increased torque implied that the composites probably have a great frictional shear force, resulting from strong adhesion at the interface between the matrix and the dispersion phase. The mechanical test indicated that the tensile strength, tensile elongation and the flexural strength of the composites were improved with the increase of the content of MAH-g-SEBS; property enhancement is attributed to improved wetting and interactions between the PP matrix and WF, which is supported by scanning electron microscopy (SEM) analysis.
引用
收藏
页码:1743 / 1752
页数:10
相关论文
共 22 条
[1]  
Avella M, 1998, J APPL POLYM SCI, V68, P1077, DOI 10.1002/(SICI)1097-4628(19980516)68:7<1077::AID-APP5>3.0.CO
[2]  
2-C
[3]   In situ compatibility of polystyrene and liquid crystalline polymer blends [J].
Chiou, YP ;
Chang, DY ;
Chang, FC .
POLYMER, 1996, 37 (25) :5653-5660
[4]   REGIME-III CRYSTALLIZATION IN POLYPROPYLENE [J].
CLARK, EJ ;
HOFFMAN, JD .
MACROMOLECULES, 1984, 17 (04) :878-885
[5]  
Fernanda M.B., 2000, POLYM TEST, V19, P625
[6]   Thermoplastic polymers reinforced with fibrous agricultural residues [J].
Georgopoulos, ST ;
Tarantili, PA ;
Avgerinos, E ;
Andreopoulos, AG ;
Koukios, EG .
POLYMER DEGRADATION AND STABILITY, 2005, 90 (02) :303-312
[7]   In situ compatibilisation of poly(phenylene sulphide) wholly aromatic thermotropic liquid crystalline polymer blends by reactive extrusion: morphology, thermal and mechanical properties [J].
Gopakumar, TG ;
Ponrathnam, S ;
Lele, A ;
Rajan, CR ;
Fradet, A .
POLYMER, 1999, 40 (02) :357-364
[8]   Deformation mechanisms and mechanical properties of modified polypropylene/wood fiber composites [J].
Hristov, VN ;
Vasileva, ST ;
Krumova, M ;
Lach, R ;
Michler, GH .
POLYMER COMPOSITES, 2004, 25 (05) :521-526
[9]   Impact fracture behavior of modified polypropylene/wood fiber composites [J].
Hristov, VN ;
Lach, R ;
Grellmann, W .
POLYMER TESTING, 2004, 23 (05) :581-589
[10]   Modified polypropylene wood flour composites. II. Fracture, deformation, and mechanical properties [J].
Hristov, VN ;
Krumova, M ;
Vasileva, S ;
Michler, GH .
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 92 (02) :1286-1292