Ureato(1-) complexes of palladium(II) and platinum(II) Crystal structure of [NBu4][(C6F5)2Pt{PhNC(O)NPr2i}]

被引：3

作者：

Ruiz, J ^{[1
]}

Rodríguez, V

Vicente, C

Pérez, J

López, G

Chaloner, PA

Hitchcock, PB

机构：

[1] Univ Murcia, Dept Quim Inorgan, Murcia 30071, Spain

[2] Univ Politecn Cartagena, Area Quim Inorgan, Dept Ingn Minera Geol & Cartog, Cartagena 30203, Spain

[3] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

INORGANICA CHIMICA ACTA | 2003年 / 351卷

关键词：

palladium complexes; platinum complexes; ureato complexes; phenylisocyanate; crystal structures;

D O I：

10.1016/S0020-1693(03)00200-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [NBu4](2)[{M(C6F5)(2)(mu-OH)}(2)] (M=Pd, Pt) with amines R2NH in the presence of the heterocumulene phenylisocyanate, PhNCO, leads to the synthesis of the ureato(1-) complexes [NBu4][M(C6F5)(2){PhNC(O)NR2}] (M = Pd, Pt). The single-crystal structure of [NBu4][(C6F5)(2)Pt{PhNC(O)NPr2i}] revealed the presence of a N,N'-chelating ureato(1-) with a 2 N(1)-Pt-N(2) bite angle of 64.0(3)degrees. (C) 2003 Elsevier B.V. All rights reserved.

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页码：114 / 118

页数：5

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