Issues and challenges of layered lithium nickel cobalt manganese oxides for lithium-ion batteries

被引：33
作者：
Chen, Shi [1 ]
Zhang, Xikun [1 ]
Xia, Maoting [1 ]
Wei, Kaiyuan [2 ]
Zhang, Liyuan [1 ]
Zhang, Xiaoqiang [2 ]
Cui, Yanhua [2 ]
Shu, Jie [1 ]
机构：
[1] Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China
[2] China Acad Engn Phys, Inst Elect Engn, Mianyang 621000, Sichuan, Peoples R China
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2021年 / 895卷
关键词：
Lithium-ion batteries; Lithium nickel cobalt manganese oxides; Cation mixing; Surface reactions; Modification method; ENHANCED ELECTROCHEMICAL PERFORMANCE; LINI0.8CO0.1MN0.1O2 CATHODE MATERIAL; NI-RICH LINI0.6CO0.2MN0.2O2; SOL-GEL METHOD; LINI0.5CO0.2MN0.3O2; CATHODE; SURFACE MODIFICATION; TRANSPORT-PROPERTIES; ELECTRODE MATERIALS; RATE CAPABILITY; SPINEL LIMN2O4;
D O I：
10.1016/j.jelechem.2021.115412
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
High energy-density lithium-ion batteries are in great demand in daily life, especially in the field of portable electronic equipment and electrical vehicles. Therefore, vigorous research and development of cathode materials with higher energy density to replace traditional ones is of great significance. In particular, compared with other cathode materials, layered lithium nickel cobalt manganese oxides (LiNixCoyMn1-x-yO2) have the advantages of low cost and high specific capacity. However, LiNixCoyMn1-x-yO2 still has serious problems in internal structure, safety and stability. Herein, the problems of LiNixCoyMn1-x-yO2 in the charging/discharging process and the research progress for improving their electrochemical performance through modification methods are summarized. The internal reaction mechanism of the battery and possible future development directions are also discussed.
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页数：12
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