Co(II)-Catalyzed Regioselective Cross-Dehydrogenative Coupling of Aryl C-H Bonds with Carboxylic Acids

被引：81

作者：

Lan, Jianyong ^{[1
]}

Xie, Haisheng ^{[1
]}

Lu, Xiaoxia ^{[2
]}

Deng, Yuanfu ^{[1
]}

Jiang, Huanfeng ^{[1
]}

Zeng, Wei ^{[1
]}

机构：

[1] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510641, Guangdong, Peoples R China

[2] Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Sichuan, Peoples R China

来源：

ORGANIC LETTERS | 2017年 / 19卷 / 16期

关键词：

CARBON-HYDROGEN BONDS; PHOSPHORAMIDATE PROTIDES; AMINATION; FUNCTIONALIZATION; SUBSTITUTION; ALKYLAMINES; ANHYDRIDES; ARYLATION; OXIDATION; CLEAVAGE;

D O I：

10.1021/acs.orglett.7b01942

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A cobalt(II)-catalyzed regioselective aryl C-H bond oxygenation between arenes and aryl or aliphatic carboxylic acids under bidendate-chelation assistance is developed. This method provides an efficient approach to acyoxy-substituted arenes with a broad range of functional group tolerance. Furthermore, this reaction system could be further applied to the preparation of polyfunctional naphthylenes

引用

页码：4279 / 4282

页数：4

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