Removal of Ionic Dyes by Nanofiber Membrane Functionalized with Chitosan and Egg White Proteins: Membrane Preparation and Adsorption Efficiency

被引：52

作者：

Chen, Yue-Sheng ^{[1
]}

Ooi, Chien Wei ^{[2
]}

Show, Pau Loke ^{[3
]}

Hoe, Boon Chin ^{[2
]}

Chai, Wai Siong ^{[3
]}

Chiu, Chen-Yaw ^{[1
]}

Wang, Steven S. -S. ^{[4
]}

Chang, Yu-Kaung ^{[1
]}

机构：

[1] Ming Chi Univ Technol, Grad Sch Biochem Engn, Dept Chem Engn, New Taipei 24301, Taiwan

[2] Monash Univ Malaysia, Sch Engn, Chem Engn Discipline & Adv Engn Platform, Jalan Lagoon Selatan, Bandar Sunway 47500, Malaysia

[3] Univ Nottingham Malaysia Campus, Fac Engn, Dept Chem & Environm Engn, Jalan Broga, Semenyih 43500, Malaysia

[4] Natl Taiwan Univ, Dept Chem Engn, Taipei 10617, Taiwan

来源：

MEMBRANES | 2022年 / 12卷 / 01期

关键词：

protein modified nanofiber membrane; chitosan; egg white proteins; removal; cationic and anionic dyes; LOW-COST ADSORBENTS; METHYLENE-BLUE DYE; ACID ORANGE 7; AQUEOUS-SOLUTIONS; METAL-IONS; WASTE; POLYACRYLONITRILE; CARBON; ISOTHERM; OXIDE;

D O I：

10.3390/membranes12010063

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Electrospun polyacrylonitrile (PAN) nanofiber membrane was functionalized with chitosan and proteins for use in the treatment of dye-containing wastewater. The PAN nanofiber membrane was subjected to alkaline hydrolysis, before being grafted with chitosan and subsequently the proteins from chicken egg white. The resultant nanofiber membrane (P-COOH-CS-CEW) was comprehensively characterized using thermogravimetric analysis, Fourier-transform infrared spectroscopy, and scanning electron microscopy. The efficiency of P-COOH-CS-CEW in removing cationic dye toluidine blue O (TBO) and anionic dye acid orange 7 (AO7) in aqueous solution was evaluated. Based on the performance of model fitting, Langmuir and pseudo-second-order kinetic model could be used to describe the performance of P-COOH-CS-CEW in the removal of TBO (pH 10) and AO7 (pH 2) from the dye solutions. The adsorbed TBO and AO7 dyes can be completely desorbed by an elution solution made of 50% (v/v) ethanol and 1 M sodium chloride. After five consecutive adsorption-desorption cycles, the efficiency of dye removal by P-COOH-CS-CEW was maintained above 97%.

引用

页数：21

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