Ultrasound aided in situ transesterification of crude palm oil adsorbed on spent bleaching clay

被引：35

作者：

Boey, Peng-Lim ^{[1
]}

Ganesan, Shangeetha ^{[1
]}

Maniam, Gaanty Pragas ^{[1
]}

Ali, Dafaalla Mohamed Hag ^{[1
,2
]}

机构：

[1] Univ Sains Malaysia, Sch Chem Sci, Minden 11800, Penang, Malaysia

[2] Sudan Univ Sci & Technol, Dept Chem, Khartoum, Sudan

来源：

ENERGY CONVERSION AND MANAGEMENT | 2011年 / 52卷 / 05期

关键词：

Spent bleaching clay; Adsorbed crude palm oil; Ultrasound; In situ transesterification; BIODIESEL PRODUCTION; SCYLLA-SERRATA; VEGETABLE-OIL; SHELL; EARTH;

D O I：

10.1016/j.enconman.2010.12.013

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Adsorbed crude palm oil on spent bleaching clay (SBC) was in situ transesterified to methyl esters (biodiesel) by the aid of ultrasound and organic co-solvents (petroleum ether (PE) or ethyl methyl ketone (EMK)). The SBC under study was found to contain 24.2-27.0% of crude oil with free fatty acids (FFA) of 3.01% and moisture content of 0.29%. The optimized reaction conditions were as follows: methanol to oil molar ratio of 150:1; catalyst (KOH), 20%; reaction temperature, 60 2 C; reaction time. 2 h. Using PE as a co-solvent, highest conversion of 75.2% was achieved while 60% was recorded with EMK. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：2081 / 2084

页数：4

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