(4,4′-dimethyl-2,2′-bipyridine)chloro-(2,2′:6′,2"-terpyridine)-iridium(III) hexafluorophosphate

被引：12
|
作者：
Yoshikawa, N [1 ]
Sakamoto, J
Kanehisa, N
Kai, Y
Matsumura-Inoue, T
Takashima, H
Tsukahara, K
机构：
[1] Nara Womens Univ, Fac Sci, Dept Chem, Nara 6308506, Japan
[2] Nara Univ Educ, Dept Chem, Nara 6308528, Japan
[3] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[4] Minerva Light Lab, Seikacyo, Kyoto 6308528, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷
关键词：
D O I：
10.1107/S1600536803019081
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [IrCl(C12H12N2)(C15H11N3)](PF6)(2), the ligand environment about the Ir atom is distorted octahedral. The 2,2':6',2"-terpyridine (terpy) ligand is coordinated in a meridional fashion, the 4,4'-dimethyl-2,2'-bipyridine (dmbpy) ligand coordinated in a cis fashion and the Cl atom is trans to one of the dmbpy N atoms. Ir-N bond distances are 1.971 (5)-2.065 (6) Angstrom and the Ir-Cl distance is 2.357 (2) Angstrom.
引用
收藏
页码：M830 / M832
页数：3
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