3D porous and 3D interpenetrating triple framework structures constructed by aurophilicity-coordination interplay in {Mn[Au(CN)2]2(H2O)2}n and {KFe[Au(CN)2]3}n

被引：44

作者：

Dong, W

Zhu, LN

Sun, YQ

Liang, M

Liu, ZQ

Liao, DZ ^{[1
]}

Jiang, ZH

Yan, SP

Cheng, P

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 20期

关键词：

D O I：

10.1039/b306026h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two cyano-bridged heterobimetallic coordination polymers {Mn[Au(CN)(2)](2)(H2O)(2)}(n) (1) and {KFe[Au(CN)(2)](3)}(n) ( 2), have been synthesized from [Au(CN)(2)](-) building blocks and structurally characterized. In both complexes aurophilicity play an important role in determining the 3D open microporous framework and the interpenetrating triple framework for 1 and 2, respectively. Both aqueous solutions of 1 and 2 display interesting luminescent properties.

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页码：2544 / 2545

页数：2

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