The copper(II) complex with two didentate Schiff base ligands. The unique rearrangment that proceeds under alcohol vapor in the solid state to construct noninclusion structure

被引：50

作者：

Shibuya, Yuhki ^{[1
]}

Nabari, Keiko ^{[1
]}

Kondo, Mitsuru ^{[1
,2
]}

Yasue, Sachie ^{[3
]}

Maeda, Kenji ^{[3
]}

Uchida, Fumio ^{[3
]}

Kawaguchi, Hiroyuki ^{[4
]}

机构：

[1] Shizuoka Univ, Grad Sch Sci, Dept Chem, Suruga Ku, Shizuoka 4228529, Japan

[2] Shizuoka Univ, Ctr Instrumental Anal, Suruga Ku, Shizuoka 4228529, Japan

[3] Fuji Chem Co Ltd, Hautform Div, Nasubigawa, Nakatsugawa 5099132, Japan

[4] Inst Mol Sci, Coordinat Chem Labs, Okazaki, Aichi 4448787, Japan

来源：

CHEMISTRY LETTERS | 2008年 / 37卷 / 01期

关键词：

D O I：

10.1246/cl.2008.78

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexation reaction of copper(II) ion and N-(m-hydroxyphenylene)salicylideneaminate (mhsa) in EtOH yields EtOH-inclusion and noninclusion crystalline samples, [Cu-(mhsa)(2)]center dot 2EtOH (1) and [Cu(mhsa)(2)] (2), respectively. The amorphous sample obtained by drying 1 rearranges to the noninclusion complex 2 under alcohol vapor in the solid state.

引用

页码：78 / 79

页数：2

共 22 条

[1] COLOUR ISOMERISM AND STRUCTURE OF SOME COPPER CO-ORDINATION COMPOUNDS .8. CRYSTAL STRUCTURE OF BIS-(N-ETHYLSALICYLALDIMINATO)COP+ER (2) [J].

BAKER, EN ;

CLARK, GR ;

HALL, D ;

WATERS, TN .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (02) :251-&

[2] COLOUR ISOMERISM AND STRUCTURE OF COPPER CO-ORDINATION COMPOUNDS .20. CRYSTAL STRUCTURE OF DI-MU-NN'-META-PHENYLENE-TETRAKIS(SALICYLIDENEIMINATO)DICOPPER(II) [J].

BEAR, CA ;

WATERS, JM ;

WATERS, TN .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (15) :2494-&

[3]

Biradha K, 2002, ANGEW CHEM INT EDIT, V41, P3395, DOI 10.1002/1521-3773(20020916)41:18<3395::AID-ANIE3395>3.0.CO

[4]

2-D

[5] COLOUR ISOMERISM AND STRUCTURE OF COPPER CO-ORDINATION COMPOUNDS .11. CRYSTAL STRUCTURE OF BIS-(N-T-BUTYLSALICYLALDIMINATO)-COPPER(2) [J].

CHEESEMA.TP ;

HALL, D ;

WATERS, TN .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (06) :685-+

[6] Anion influence on the structures of a series of copper(II) metal-organic frameworks [J].

Díaz, P ;

Benet-Buchholz, J ;

Vilar, R ;

White, AJP .

INORGANIC CHEMISTRY, 2006, 45 (04) :1617-1626

[7] Synthesis and structural characterization of a novel mixed-valent CuIICuICuII triangular metallomacrocycle using an imine-based rigid ligand [J].

Guo, D ;

Qian, CQ ;

Duan, CY ;

Pang, KL ;

Meng, QJ .

INORGANIC CHEMISTRY, 2003, 42 (06) :2024-2030

[8] Functional micropore chemistry of crystalline metal complex-assembled compounds [J].

Kitagawa, S ;

Kondo, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (08) :1739-1753

[9] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[10] Dynamic coordination polymers with 4,4′-oxybis(benzoate):: Reversible transformations of nano- and nonporous coordination frameworks responding to present solvents [J].

Kondo, M ;

Irie, Y ;

Shimizu, Y ;

Miyazawa, M ;

Kawaguchi, H ;

Nakamura, A ;

Naito, T ;

Maeda, K ;

Uchida, F .

INORGANIC CHEMISTRY, 2004, 43 (20) :6139-6141

← 1 2 3 →