Low-temperature growth and optical properties of ZnO nanorods

被引:72
作者
Yang, Jinghai [1 ,2 ]
Lang, Jihui [1 ]
Yang, Lili [1 ,2 ,3 ]
Zhang, Yongjun [1 ]
Wang, Dandan [1 ]
Fan, Hougang [1 ]
Liu, Huilian [1 ,2 ,3 ]
Wang, Yaxin [1 ]
Gao, Ming [1 ]
机构
[1] Jilin Normal Univ, Inst Condensed State Phys, Siping 136000, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Key Lab Excited State Proc, Changchun 130033, Peoples R China
[3] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
关键词
ZnO nanorods; chemical solution deposition; photoluminescence;
D O I
10.1016/j.jallcom.2006.12.135
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Zinc oxide (ZnO) nanorods were grown on ITO conducting glass by the chemical solution deposition method (CBD) in an aqueous solution that contained zinc nitrate hexahydrate (Zn(NO3)(2).6H(2)O) and methenamine (C6H12N4). The size of ZnO nanorods increased with molar concentration of zinc nitrate, and the nanorods with different aspect ratios also formed through tuning the reaction time when the molar concentration was 0.1 M. The length of nanorods increased significantly with the reaction time, but the thickness of the film deposited on the substrate only slightly increased. From the X-ray measurement results, it can be seen that the growth orientation of the as-prepared ZnO nanorods was [0 0 2]. Photoluminescence measurements were also carried out, the result showed a blue shift in violet emission with the reduction in crystal size. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:521 / 524
页数:4
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