Synthesis and Crystal Structures of Two Coordination Polymers Based on a New N-Donor Aromatic Ligand

被引：2

作者：

Zhao, D. ^{[1
]}

Ma, F. X. ^{[1
]}

Zhang, R. H. ^{[1
]}

机构：

[1] Henan Polytech Univ, Coll Chem & Chem Engn, Jiaozuo, Peoples R China

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 59卷 / 07期

基金：

中国国家自然科学基金;

关键词：

hydrothermal; coordination polymer; X-ray diffraction; layer structure; hydrogen bond; NICKEL(II); COMPLEXES;

D O I：

10.1134/S0022476618070223

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new coordination polymers Co(C9H7N7)(SO4)(H2O) (I) and Cd(C9H6N7)(2) H 2O (II), where C9H7N7 is 4-(5-(1H-1,2,4-triazol-1-ylmethyl)-1,2,4-triazol-3-yl)pyridine, are synthesized through hydrothermal reactions and structurally determined by single-crystal X-ray diffraction analyses. The results reveal that compound I belongs to the triclinic space group P-1 with a 1-D chain structure, whereas compound II belongs to the monoclinic space group C2 with a 2D layer structure. Hydrogen bonds play an important role in the construction of 3D structure of the two compounds.

引用

页码：1678 / 1683

页数：6

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