Reductive cleavage and related reactions leading to molybdenum-element multiple bonds: new pathways offered by three-coordinate molybdenum(III)

被引：168
作者：
Cummins, CC [1 ]
机构：
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
来源：
CHEMICAL COMMUNICATIONS | 1998年 / 17期
关键词：
D O I：
10.1039/a802402b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three-coordinate molybdenum(III) complexes comprise a new class of reactive-yet-isolable substances. Related to a well known class of metal-metal triple bonded dimers, the monomeric molybdenum(III) complexes supported by sterically-demanding N-tert-alkylanilide ligands offer previously unavailable synthetic routes to molybdenum-element multiple bonds. Terminal nitride, phosphide and carbide functionalities have been prepared from reactions with dinitrogen, white phosphorus and carbon monoxide, respectively.
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页码：1777 / 1786
页数：10
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