We consider the efficacy of using luminosity distance measurements of deep redshift supernovae to discriminate between two forms of dark energy, quintessence (a scalar field with canonical kinetic terms rolling down a potential) and k-essence (a scalar field whose cosmic evolution is driven entirely by nonlinear kinetic terms). The primary phenomenological distinction between the two types of models that can be quantified by supernova searches (at least in principle) is that the evaluation of state w = p/rho of quintessence is falling today while that of k-essence is rising. By simulating 10(5) possible datasets that SNAP could obtain, we show that even if the mass density Ohm (m) is known exactly, an ambiguity remains that may not allow a definitive distinction to be made between the two types of theories. (C) 2001 Published by Elsevier Science B.V.