Electrode based on porous MXene nanosheets for high-performance supercapacitor

被引：15

作者：

Guan, Guozhen ^{[1
]}

Li, Peixuan ^{[1
]}

Shi, Xin ^{[1
]}

Lu, Lei ^{[1
]}

Fan, Yuchao ^{[1
]}

Xu, Jie ^{[1
]}

Shang, Yuanyuan ^{[1
]}

Zhang, Yingjiu ^{[1
]}

Wei, Jinquan ^{[2
]}

Guo, Fengmei ^{[1
]}

机构：

[1] Zhengzhou Univ, Sch Phys & Microelect, Key Lab Mat Phys, Minist Educ, Zhengzhou 450001, Peoples R China

[2] Tsinghua Univ, Sch Mat Sci & Engn, Key Lab Adv Mat Proc Technol, State Key Lab New Ceram & Fine Proc,Educ Minist, Beijing 100084, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2022年 / 924卷

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

MXene; Porous nanosheets; Supercapacitors; Electrode materials;

D O I：

10.1016/j.jallcom.2022.166647

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

MXenes, a family of the typical two-dimensional materials, that are considered to be an excellent candidate material for supercapacitors, due to their large surface area, high conductivity and high specific pseudocapacitance. However, when assembled into electrode, MXene nanosheets are easy to aggregate because of the strong Van der Waals force. The assembled dense structure will limit the transport of electrolyte, decrease the active sites and electrochemical performance. In this work, in order to suppress the self-restacking of nanosheets and introduce more electrolyte transport channels, Ti3C2Tx nanosheets are partially oxidized and etched to get porous nanosheets. Film electrode based on porous Ti3C2Tx nanosheets shows higher specific surface area (48.3 m2/g) and improved electrochemical performance, including a high specific capacitance of 385 F/g at 1 A/g and good cycle stability of 92 % after 10,000 CV cycles at 100 mV/s. (c) 2022 Published by Elsevier B.V.

引用

页数：9

共 49 条

[1] Polypyrrole/carbon nanotube supercapacitors: Technological advances and challenges [J].