Colorless transparent fluorescence material: Sintered porous glass containing rare-earth and transition-metal ions

被引:88
作者
Chen, DP
Miyoshi, H
Akai, T [1 ]
Yazawa, T
机构
[1] Natl Inst Adv Ind Sci & Technol, Ikeda, Osaka 5638577, Japan
[2] JST, PRESTO, Convers & Control Adv Chem, Ikeda, Osaka 5638577, Japan
[3] Himeji Inst Technol, Himeji, Hyogo 6712201, Japan
关键词
D O I
10.1063/1.1946897
中图分类号
O59 [应用物理学];
学科分类号
摘要
Transparent fluorescence oxide glass with high emission yields has been prepared. Porous glass was impregnated with rare-earth and transition-metal ions and consequently sintered at 1100 degrees C into a compact nonporous glass. Reduction sintering is indispensable for obtaining fluorescence glass with high emission yield. Sintering of glass impregnated with Eu ions in a reducing atmosphere enhances the emission intensity by about 15 times than that sintered in air. The Eu2+ and Ce3+ ions and Sn2+ and Cu+ ions incorporated in SiO2 glass obtained by reduction sintering exhibit intense fluorescence in the near-ultraviolet and visible ranges, their emission yields are 97%, 70%, 100%, and 90%, respectively. (c) 2005 American Institute of Physics.
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页码:1 / 3
页数:3
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