On the Interaction Between Nicotine and Metal(II) Ions in Aqueous Solutions

被引：4
作者：
Manfredi, C. [1 ]
Vero, S. [1 ]
Vasca, E. [2 ]
Perrotta, D. [1 ]
Trifuoggi, M. [1 ]
Sorrentino, I. [1 ]
Ferri, D. [1 ]
机构：
[1] Univ Naples Federico II, Dept Chem Sci, Via Cintia, I-80126 Naples, Italy
[2] Univ Salerno, Dipartimento Chim & Biol, Via Ponte Don Melillo, I-84084 Salerno, Italy
来源：
JOURNAL OF SOLUTION CHEMISTRY | 2016年 / 45卷 / 07期
关键词：
Nicotine; Hydrolysis; Equilibrium analysis; Metal (II)/nicotine complexes; Potentiometry; UV/Vis absorption; OXIDATIVE STRESS; NEUROTOXICITY; HYDROLYSIS;
D O I：
10.1007/s10953-016-0483-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A chemical investigation of the interaction mechanisms of nicotine with the metal(II) ions Pb, Fe, and Cu is reported. The complex formation between nicotine and metal(II) has been investigated at 25.00 0.02 C, in constant ionic medium (as sodium perchlorate, or sodium chloride), by UV/Vis spectrophotometric and potentiometric methods. The experimental method consists of coulometric or volumetric titrations. The protolysis constants of nicotine have been determined under the same experimental conditions. The pH investigated spans between 3 and 10. By using the specific ion interaction theory the conditional constants of nicotine have been extrapolated at zero ionic strength. The results of the graphical and numerical methods adopted indicate, for all the systems investigated, the formation of a predominating Me(II)/nicotine mononuclear complexes.
引用
收藏
页码：971 / 989
页数：19
相关论文
共 50 条
  • [21] Generation of Reactive Oxygen Species by Interaction between Antioxidants Used as Food Additive and Metal Ions
    Iwasaki, Yusuke
    Oda, Momoko
    Tsukuda, Yuri
    Nagamori, Yuki
    Nakazawa, Hiroyuki
    Ito, Rie
    Saito, Koichi
    [J]. FOOD HYGIENE AND SAFETY SCIENCE, 2014, 55 (04): : 167 - 176
  • [22] Adsorption of Nicotine from Aqueous Solutions on Montmorillonite and Acid-Modified Montmorillonite
    Ilic, Irena
    Jovic-Jovicic, Natasa
    Bankovic, Predrag
    Mojovic, Zorica
    Loncarevic, Davor
    Grzetic, Ivan
    Milutinovic-Nikolic, Aleksandra
    [J]. SCIENCE OF SINTERING, 2019, 51 (01) : 93 - 100
  • [23] Electrochemical Investigation of Amoxicillin Interaction with Some Metal Ions Related to Complexation Process
    Hrioua, A.
    Aghris, S.
    Ajermoun, N.
    Ettadili, F.
    Farahi, A.
    Lahrich, S.
    Bakasse, M.
    Saqrane, S.
    El Mhammedi, M. A.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2020, 167 (12)
  • [24] NMR Characterization of the Interaction of the Endonuclease Domain of MutL with Divalent Metal Ions and ATP
    Mizushima, Ryota
    Kim, Ju Yaen
    Suetake, Isao
    Tanaka, Hiroaki
    Takai, Tomoyo
    Kamiya, Narutoshi
    Takano, Yu
    Mishima, Yuichi
    Tajima, Shoji
    Goto, Yuji
    Fukui, Kenji
    Lee, Young-Ho
    [J]. PLOS ONE, 2014, 9 (06):
  • [25] Biological Interaction Between Copper(II) Complex and Nucleosides
    Guo, Yaping
    Wang, Xiuju
    Luo, Leiming
    Du, Jinge
    Shang, Xuefang
    [J]. ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (14) : 4457 - 4461
  • [26] Zinc(II) complexes with hydroxocarboxylates and mixed metal species with tin(II) in different salts aqueous solutions at different ionic strengths: formation, stability, and weak interactions with supporting electrolytes
    Cigala, Rosalia Maria
    Crea, Francesco
    De Stefano, Concetta
    Foti, Claudia
    Milea, Demetrio
    Sammartano, Silvio
    [J]. MONATSHEFTE FUR CHEMIE, 2015, 146 (04): : 527 - 540
  • [27] Mononuclear and dinuclear mechanisms for catalysis of phosphodiester cleavage by alkaline earth metal ions in aqueous solution
    Kirk, Brittany A.
    Cusack, Corey L.
    Laager, Eric
    Rochlis, Evan
    Thomas, Terace
    Cassano, Adam G.
    [J]. JOURNAL OF INORGANIC BIOCHEMISTRY, 2010, 104 (02) : 207 - 210
  • [28] Selective Conversion of Glucose into Lactic Acid with Transition Metal Ions in Diluted Aqueous NaOH Solution
    Huo, Zhibao
    Fang, Yan
    Ren, Dezhang
    Zhang, Song
    Yao, Guodong
    Zeng, Xu
    Jin, Fangming
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2014, 2 (12): : 2765 - 2771
  • [29] Complex Formation Between Ferric(III), Chromium(III), and Cupric(II) Metal Ions and (O,N) and (O,O) Donor Ligands with Biological Relevance in Aqueous Solution
    Ahmed E. Fazary
    Erzalina Hernowo
    Artik Elisa Angkawijaya
    Tse-Chuan Chou
    Chih Hung Lin
    Mohamed Taha
    Yi-Hsu Ju
    [J]. Journal of Solution Chemistry, 2011, 40 : 1965 - 1986
  • [30] Complex Formation Between Ferric(III), Chromium(III), and Cupric(II) Metal Ions and (O,N) and (O,O) Donor Ligands with Biological Relevance in Aqueous Solution
    Fazary, Ahmed E.
    Hernowo, Erzalina
    Angkawijaya, Artik Elisa
    Chou, Tse-Chuan
    Lin, Chih Hung
    Taha, Mohamed
    Ju, Yi-Hsu
    [J]. JOURNAL OF SOLUTION CHEMISTRY, 2011, 40 (12) : 1965 - 1986
12345